No abstract

To improve the efficiency of bioethanol production, an advanced process was required to extract ethanol from solid-state fermented feedstock. With regard to the characteristics of no fluidity of solid biomass, a continuous solid-state distillation (CSSD) column was designed with a proprietary rotary baffle structure and discharging system. To optimize the operation condition, fermented sweet sorghum bagasse was prepared as feedstock for a batch distillation experiment. The whole distillation time was divided into heating and extracting period which was influenced by loading height and steam flow rate simultaneously. A total of 16 experiments at four loading height and four steam flow rate levels were conducted, respectively. Referring to packing, rectifying column, mass, and heat transfer models of the solid-state distillation heating process were established on the basis of analyzing the size distribution of sweet sorghum bagasse. The specific heat capacity and thermal conductivity value of fermented sweet sorghum bagasse were tested and served to calculate the ethanol yielding point and concentration distribution in the packing. The extracting process is described as the ethanol desorption from porous media absorbent and the pseudo-first-order desorption dynamic model was verified by an experiment. Benefit (profit/time) was applied as objective function and solved by successive quadratic programming. The optimal solution of 398 mm loading height and 8.47 m3/h steam flow rate were obtained to guide a 4 m in diameter column design. One heating and two extracting trays with 400 mm effective height were stacked up in an industrial CSSD column. The steam mass flow rate of 0.5 t/h was determined in each tray and further optimized to half the amount on the third tray based on desorption equation.

The technology for producing bioethanol from sweet sorghum stalks by solid-state fermentation has developed rapidly in recent years, and has many similarities with traditional Chinese liquor production. However, the product from sweet sorghum stalks was lacking in volatile flavors, and the level of harmful contents were uncertain, therefore it could not be sold as liquor. In this study, the protein, fat, and tannin in the clusters and leaves of sweet sorghum were utilized to increase the content of flavor compounds in the ethanol product through the anaerobic fermentation of Saccharomyces cerevisiae. Meanwhile, the silage fermentation method was used to extend the preservation time of the raw materials and to further enhance the flavors of Fen-flavor liquor, with ethyl acetate as the characteristic flavor. The effects of different feedstock groups on ethyl acetate, ethyl lactate, methanol, acetaldehyde, acetal, fusel oil, total acid, and total ester were evaluated by analyzing the chemical composition of different parts of sweet sorghum and determined by gas chromatograph. The effect of different fermentation periods on the volatile flavor of sweet sorghum Baijiu was evaluated. The yield of the characteristic volatile flavor was increased by the extension of the fermentation time. Sweet sorghum Baijiu with a high ester content can be used as a flavoring liquor, blended with liquor with a shorter fermentation period to prepare the finished Fen-flavor Baijiu, conforming to the Chinese national standard for sale.

Extracting ethanol by steam directly from fermented solid-state bagasse is an emerging technology of energy-efficient bioethanol production. With continuous solid-state distillation (CSSD) approach, the vapor with more than 25 wt% ethanol flows out of the column. Conventionally, the vapor was concentrated to azeotrope by rectification column, which contributes most of the energy consumption in ethanol production. As an alternative, a process integrating CSSD and vapor permeation (VP) membrane separation was tested. In light of existing industrial application of NaA zeolite hydrophilic membrane for dehydration, the prospect of replacing rectification operation with hydrophobic membrane for ethanol enriching was mainly analyzed in this paper. The separation performance of a commercial PDMS/PVDF membrane in a wide range of ethanol–water-vapor binary mixture was evaluated in the experiment. The correlation of the separation factor and permeate flux at different transmembrane driving force was measured. The mass and energy flow sheet of proposed VP case and rectification case were estimated respectively with process simulation software based on experimental data. Techno-economic analysis on both cases was performed. The results demonstrated that the additional VP membrane cost was higher than the rectification column, but a lower utilities cost was required for VP. The discount payback period of supplementary cost for VP case was determined as 1.81 years compared with the membrane service lifetime of 3 years, indicating that the hybrid CSSD-VP process was more cost effective and energy efficient.