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A new photoresponsive bent‐core nematic (BCN) material, which exhibits flexoelectric domains (FDs) driven by electric field, is reported. Unexpectedly, it is found that the morphologies of FDs can be controlled by irradiation with light fields. This light tunability is ascribed to the photoisomerization effect of the azo moiety within the BCN molecules, where the ratio of trans and cis isomers changes according to the parameters of the light field, resulting in adjustable electric threshold and periodicity of FDs. Based on this principle, a prototype of controllable optical grating is assembeled, whose operation can be manipulated by the wavelength or intensity of light. Due to the easy, instant, and remote operation by light, this optical, contactless tunability has a great advantage over traditional electric control in tunable photonic devices.

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The influence of UV light-induced pitch contraction and dilation on the electroconvection patterns (ECPs) of a chiral nematic liquid crystal containing a photoresponsive chiral dopant is investigated in planar-aligned cells. It is observed that the helical twisting power of the dopant changes (even undergoes handedness inversion) under UV irradiation; consequently, the pitch and the direction of the convection rolls in ECPs (being either parallel with or perpendicular to the surface alignment) could be controlled by the UV intensity and the ac voltage. In contrast to traditional methods, where the pitch is modulated by electric or thermal fields, our method of applying a light field allows a remote and contactless manipulation of the pitch, which is easily detectable via the morphological changes of ECPs. The ability to control the orientation of ECPs by tuning the light intensity can conveniently be utilized as an optical grating, allowing switchable, dual-mode operation.

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