In general, synthetic textiles have many advantages of high modulus and strength, stiffness, stretch, wrinkle and abrasion resistances, relatively low cost, convenient processability, tailorable performance and easy recycling [1,2]. On the other hand, they have low wettability because of inherently hydrophobicity, which leads to less wearing comfort, low color strength, build-up of electrostatic charge, the tendency to pilling and insufficient washability [2,3]. Because of these disadvantages, surface modification to enhance hydrophilicity has been carried out by conventional chemical modifications [4][5][6][7]. The chemical modification can improve textile-specific performance by altering its chemical structure due to a chemical reaction, such as esterification, grafting, and crosslinking. Therefore, large amounts of modifying agents and solvents are required, resulting in undesired high-cost drying and pollutanttreating steps [4,7]. As alternative environmentally friendly technology, dry gas-phase oxidation of synthetic fiber surfaces after processing has been recently attempted by ultraviolet light [8][9][10][11][12][13] and plasma [7,[14][15][16][17][18][19][20] technologies.Recently, we have carried out the surface oxidation of synthetic fibers by two dry processes in the atmosphere. Some synthetic textiles were treated by 172 nm ultraviolet (UV) excimer light irradiation [21]. As a result, the water absorbency for any fabric was enhanced because of the increase in single fiber wettability. Such a tendency was remarkable for polyester, which surface oxygen concentration and roughness much increased due to UV exposure compared with other synthetic fibers. The color strength after dyeing and the detergency by laundering were also improved after UV irradiation for the polyester fabric [22]. Moreover, we have applied atmospheric pressure plasma (APP) to polyester textile finishing. The APP jet device used has attracted significant attention, because they generate plasma plumes in open space, have no limitations on the sizes of the objects to be treated and can achieve continuous in-line material processing at high speed [23][24][25][26][27]. To obtain basic information on physicochemical properties of the treated surface, the PET film with geometric simplicity was chosen [28,29]. The increases in wettability and surface free energy were remarkable for the APP treatment in comparison with the UV treatment, which was not in contradiction with the results characterized by X-ray photoelectron spectroscopy. Using polyester fabric, it was confirmed that the APP jet treatment increased oxygen concentration and roughness Abstract: Three synthetic textiles, polyester, nylon 6 and acetate fabrics, were treated by atmospheric pressure plasma (APP) jet with nitrogen gas. From the contact angle measurements using a single fiber, the wettability and the base parameter of surface free energy of the three fibers were found to increase drastically after the APP treatment. X-ray photoelectron spectroscopy and atomic force micros...