This study is focused on a hybrid fuel cell/gas turbine (FC/GT) system with an atmospheric pressure solid oxide fuel cell (SOFC). The impact of the gas turbine rotational speed on dynamic performance and controllability of a hybrid system is investigated. The transient response of the FC/GT system to perturbations in the power demand has been investigated. Two operational strategies of gas turbines are compared: (1) fixed speed operation, and (2) variable speed operation. For both operation strategies, a wide range of power production is numerically simulated. The results show that variable speed operation is superior for the FC/GT hybrid configuration studied. Variable speed operation allows a 50% turn down in power with no additional balance of plant equipment required. The system efficiency is maintained above 66% for variable speed operation compared to 53% for fixed speed operation with auxiliary combustion.

A bottoming 275 kilowatt planar solid oxide fuel cell (SOFC) gas turbine (GT) hybrid system control approach has been conceptualized and designed.Based on previously published modeling techniques, a dynamic model is developed that captures the physics sufficient for dynamic simulation of all processes that affect the system with time scales greater than ten milliseconds. The dynamic model was used to make system design improvements to enable the system to operate dynamically over a wide range of power output (15 to 100% power). The wide range of operation was possible by burning supplementary fuel in the combustor and operating the turbine at variable speed for improved thermal management.The dynamic model was employed to design a control strategy for the system. Analyses of the relative gain array (RGA) of the system at several operating points gave insight into input/output (I/O) pairing for decentralized control. Particularly, the analyses indicate that for SOFC/GT hybrid plants that use voltage as a controlled variable it is beneficial to control system power by manipulating fuel cell current and to control fuel cell voltage by manipulating the anode fuel flowrate. To control the stack temperature during transient load changes, a cascade control structure is employed in which a fast inner loop that maintains the GT shaft speed receives its setpoint from a slower outer loop that maintains the stack temperature. Fuel can be added to the combustor to maintain the turbine inlet temperature for the lower operating power conditions. To maintain fuel utilization and to prevent fuel starvation in the fuel cell, fuel is supplied to the fuel cell proportionally to the stack current. In addition, voltage is used as an indicator of varying fuel concentrations allowing the fuel flow to be adjusted accordingly. Using voltage as a sensor is shown to be a potential solution to making SOFC systems robust to varying fuel compositions.The simulation tool proved effective for fuel cell/GT hybrid system control system development. The resulting SOFC/GT system control approach is shown to have transient load-following capability over a wide range of power, ambient temperature, and fuel concentration variations.

CO2 capture and sequestration (CCS) from stationary flue gas sources is one of the critical technologies needed as the future energy landscape shifts to low carbon intensity energy systems. Molten carbonate fuel cells (MCFCs) have the potential to capture CO2 from flue gas at higher thermal efficiency than traditional CCS technologies while simultaneously producing electricity. Herein, we present an investigation of molten carbonate fuel cell behavior at carbon capture conditions using simulated natural gas combined cycle flue gas. Measurements at these low CO2 and high current conditions reveal a lower than expected cathodic consumption of CO2 Based on the strong dependence of this deviation on water partial pressure as well as mass balances revealing a net consumption of water at the cathode, a parallel oxygen reduction mechanism is proposed. In this mechanism, water and oxygen are consumed at the cathode to produce hydroxide ions which migrate through the electrolyte to the anode. This parallel mechanism contributes to power generation but not to CO2 capture. Mass transport limitations in the molten carbonate fuel cell cathode were identified as the primary driver for this alternative mechanism which were heavily influenced by the design of the current collector and cathode interface.

A nonlinear mathematical model of an internal reforming molten carbonate fuel cell stack is developed for control system applications to fuel cell power plants. The model is based on principles of energy and mass component balances and thermochemical properties. Physical data for this model is obtained from a 2-MW system design that is a precursor to a demonstration fuel cell power plant running on natural gas at the City of Santa Clara, CA. The model can be used to provide realistic evaluations of the responses to varying load demqnds on the fuel cell stack and to define transient limitations and control requirements. Simulation results are presented for a transient response to a power plant trip at full load

Molten Carbonate Fuel Cells (MCFCs) are commercially employed in MW-scale power production, and recently are being developed also for carbon capture. Past experiments showed that MCFC performance with wet cathode feeding was higher than with dry cathode feeds at otherwise similar conditions. This was ascribed to a mechanism that predicted the water increasing the apparent CO 2 diffusion rate. However, recent tests performed at low CO 2 cathode feed concentrations, as in carbon capture service, showed the emergence of a different water effect. Namely, there seems to be an electrochemical reaction path attributable to water, involving hydroxide ions that runs parallel with the main path involving CO 2 . This results in lower CO 2 transfer from the cathode to the anode than what can be calculated from the electrical current. For the first time, here, a theoretical analysis will be presented to introduce a kinetic expression for MCFCs working under this dual-ion regime. Focus will be given to the expression of CO 2 and water polarization to assess the ratio between the current due to the two anions. Simulation and experimental results will be discussed providing a reliable and effective basis for the performance optimization of the MCFCs both in power and in carbon capture applications.