If Lo and Vo are constant, the value of C appearing in eq 2 and 3 is a constant. Slight variations in Lo and Vo affect C as shown in eq A2. This variation of C can be accounted for in eq 2 and 3.On the Kinetics and Mechanism of the Thermal Decomposition of Methane in a Flow System1 by .

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The recent work of Bell and Kistiakowsky2 allows one to compute //°2as for the reaction CH4 -> CH2 + ,(1) with fair accuracy. It is 103 keal., with an uncertainty of 3 or 4 keal. This may be compared with the AH°2as of about 102 keal.3 for the reaction CH4 -> CH3 + H(2)

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