Vinyltrichlorosilane has been prepared by the abstraction of hydrogen chloride from chloroethyltrichlorosilane (1) as well as by the high temperature interaction of vinyl chloride and a silicon alloy (1-4).In this work, vinyltrichlorosilane was allowed to react with the proper Grignard reagent to form vinyltrimethylsilane and its triethyl, tri-n-propyl, tri-nbutyl, and tri-n-amyl homologs. Vinyltriallylsilane, vinyltriphenylsilane, and

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1. By direct halogenation in carbon tetrachloride, the following have been prepared: triethylchlorosilane, tribenzylchlorosilane, triethylbromosilane, tricyclohexylbromosilane, and tribenzylbromosilane.2. Benzoyl chloride has been found to react with tribenzylsilane to form benzaldehyde and tribenzylchlorosilane. With triethylsilane a comparable reaction

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