The use of molecular modulators to reduce the defect density at the surface and grain boundaries of perovskite materials has been demonstrated to be an effective approach to enhance the photovoltaic performance and device stability of perovskite solar cells. Herein, we employ crown ethers to modulate perovskite films, affording passivation of undercoordinated surface defects. This interaction has been elucidated by solid-state nuclear magnetic resonance and density functional theory calculations. The crown ether hosts induce the formation of host–guest complexes on the surface of the perovskite films, which reduces the concentration of surface electronic defects and suppresses nonradiative recombination by 40%, while minimizing moisture permeation. As a result, we achieved substantially improved photovoltaic performance with power conversion efficiencies exceeding 23%, accompanied by enhanced stability under ambient and operational conditions. This work opens a new avenue to improve the performance and stability of perovskite-based optoelectronic devices through supramolecular chemistry.

The fact that the clustering of dark matter halos depends not only on their mass, but also the formation epoch, is a prominent, albeit subtle, feature of the cold dark matter structure formation theory, and is known as assembly bias. At low mass scales (∼ 10 12 h −1 M ⊙ ), early-forming halos are predicted to be more strongly clustered than the late-forming ones. In this study we aim to robustly detect the signature of assembly bias observationally, making use of formation time indicators of central galaxies in low mass halos as a proxy for the halo formation history. Weak gravitational lensing is employed to ensure our early-and late-forming halo samples have similar masses, and are free of contamination of satellites from more massive halos. For the two formation time indicators used (resolved star formation history and current specific star formation rate), we do not find convincing evidence of assembly bias. For a pair of early-and late-forming galaxy samples with mean mass M 200c ≈ 9 × 10 11 h −1 M ⊙ , the relative bias is 1.00 ± 0.12. We attribute the lack of detection to the possibilities that either the current measurements of these indicators are too noisy, or they do not correlate well with the halo formation history. Alternative proxies for the halo formation history that should perform better are suggested for future studies.

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