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In this study, a reformer stack was made by incorporating silicon technology into catalyst preparation. The volumes of an individual micro-channel chip and a whole reformer stack were 0.4 cm3 and 16 cm3, respectively. Different weight ratios (B/C  =  35, 15, 5, and 0 wt%) of binder (a mixture of boehmite, bentonite, and deionized water) and catalyst were mixed to find out the optimal adhesion between the catalyst and silicon substrate. The results from this study show that the percentage of weight loss of the catalyst on the silicon substrate increases as the concentration of inorganic binder decreases. To further increase the exposed surface area of the catalyst deposited on the micro-channels, micro-column structures were integrated into the channels; however, a blockage of the catalysts among the columns during deposition was encountered. To resolve this issue, a method of pre-protecting the micro-channel with thick-film photoresist was utilized for the catalyst deposition, and the performance of the fabricated micro-column reformer was able to reach a 95% methanol conversion rate, 90% hydrogen selectivity, and 1.6  ×  10−5 (mol min−1) hydrogen yield at 225 °C in the partial oxidation of methanol reaction.

In the present study, a novel micro-channel methanol reformer with a finger-shaped groove structure was successfully demonstrated to enhance the methanol conversion rate � nd the hydrogen yield. By introducing a centrifugal techlllq � e, a porous and gr � dien � d . istribution of the catalyst layer thIckness can be obtamed mSlde the micro-channels so as to force the methanol steam to react sufficiently with high surface area catalysts. As the ratio of binder to catalysts varied from . 6� to 0, the methanol conversion rate, hydrogen selectiVIty and hydrogen yield of the micro-methanol reformer at 250°C can approach �100%, 92% and 1.56xlO-5 mole min-I , respectively. Moreover, a high perfonnance output can still be obtained even at 200°C, which is superior to our previous studies .