A 1,3-butadiyne-linked diruthenium complex 4 is successfully brought onto the gold surface in a lying flat mode to form self-assembled monolayers (SAMs) showing reversible multiple redox behaviors on the electrode surface. The diruthenium species with different oxidation states, particularly the Ru(2)(III,III) state which is unstable and impossible to isolate from the solution, can be detected by in situ IR spectroscopy.

The preparation and properties of a new cyano complex containing the Ru3(μ3-O) core, [Ru3(μ3-O)(μ-CH3COO)6(py)2(CN)] (1; py = pyridine), are reported. Complex 1 in CH2Cl2 showed intense absorption bands at 244, 334, and 662 nm, corresponding to a π-π* transition of the ligand, cluster-to-ligand charge transfer, and intracluster transitions, respectively. The cyclic voltammogram of 1 in 0.1 M (n-Bu)4NPF6-CH2Cl2 showed redox waves for the processes Ru3(II,II,III)/Ru3(II,III,III), Ru3(II,III,III)/Ru3(III,III,III), and Ru3(III,III,III)/Ru3(III,III,IV) at E1/2 = -1.49, -0.26, and +1.03 V vs Ag/AgCl, respectively. The first two redox potentials are more negative by ca. 0.2 V in comparison with the corresponding potentials of [Ru3(μ3-O)(μ-CH3COO)6(py)3](+). This is in sharp contrast to the positive shifts of the corresponding waves of [Ru3(II,III,III)(μ3-O)(μ-CH3COO)6(py)2(CO)]. Density functional theory (DFT) calculations of [Ru3(II,III,III)(μ3-O)(μ-CH3COO)6(py)3], [Ru3(II,III,III)(μ3-O)(μ-CH3COO)6(py)2(CN)](-), and [Ru3(II,III,III)(μ3-O)(μ-CH3COO)6(py)2(CO)] showed that the positive charge of the ruthenium is delocalized over the triruthenium cores of the first two and is localized as Ru(II)(CO){Ru(III)(py)}2 in the CO complex. The calculations explain the difference in the π interactions of the two ligands with the triruthenium cores.

A new μ-oxo-bis(μ-acetato)diruthenium(III) complex bearing two pyridyl disulfide ligands {[Ru2(μ-O)(μ-OAc)2(bpy)2(L(py-SS))2](PF6)2 (OAc = CH3CO2(-), bpy = 2,2'-bipyridine, L(py-SS) = (C5H4N)CH2NHC(O)(CH2)4CH(CH2)2SS) (1)} has been synthesized to prepare self-assembled monolayers (SAMs) on the Au(111) electrode surface. The SAMs have been characterized by contact-angle measurements, reflection-absorption surface infrared spectroscopy, cyclic voltammetry, and reductive desorption experiments. The SAMs exhibited proton-coupled electron transfer (PCET) reactions when the electrochemistry was studied in aqueous electrolyte solution (0.1 M NaClO4 with Britton-Robinson buffer to adjust the solution pH). The potential-pH plot (Pourbaix diagram) in the pH range from 1 to 12 has established that the dinuclear ruthenium moiety was involved in the interfacial PCET processes with four distinct redox states: Ru(III)Ru(III)(μ-O), Ru(II)Ru(III)(μ-OH), Ru(II)Ru(II)(μ-OH), and Ru(II)Ru(II)(μ-OH2). We also demonstrated that the interfacial redox processes were modulated by the addition of Lewis acids such as BF3 or Al(3+) to the electrolyte media, in which the externally added Lewis acids interacted with μ-O of the dinuclear moiety within the SAMs.

The music recommender system can help us extract valuable music from a huge amount of raw information, due to the increasingly severe data sparsity and cold start problems in music recommendation system, the recommendation results will be inaccurate. But the traditional algorithm cannot effectively solve these problems; the existing improved algorithm still requires specific parameters in advance due to its poor stability. In this paper, a proposition for a cold start based on community detection algorithm is proposed. By projecting the bipartite network, calculating the similarity between the User and the Item, the Louvain algorithm is used to perform community detection on the projected One-mode network, so that the new record can be updated to the original community, and then the user group is recommended for music. With higher accuracy, solid stability, and shorter running time (when compared with other ease cold start algorithms), the algorithm in the larger community can be safely applied to the music recommendation system or prediction field.

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