A heterometallic aggregation of {Co11Cd6} can be hierarchical built from a {Co14} precursor directly. HRESI-MS technique was used to track the stepwise Cd2+-capture: {Co14} → {Co8} → {Co8Cd2} → {Co8Cd3} → {Co8Cd4} → {Co8Cd5} → {Co8Cd6} → {Co11Cd6}.
A novel discrete {Co14Mo24} nanoscaled cluster, with a triangle Co4 core encapsulated in two novel capped Co-substituted Keggin-type Co5Mo12O40 anions, was isolated from alkaline methanol solution. And the HRESI-MS of {Co14Mo24} cluster was recorded.
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