A new quark-field smearing algorithm is defined which enables efficient calculations of a broad range of hadron correlation functions. The technique applies a low-rank operator to define smooth fields that are to be used in hadron creation operators. The resulting space of smooth fields is small enough that all elements of the reduced quark propagator can be computed exactly at reasonable computational cost. Correlations between arbitrary sources, including multihadron operators can be computed a posteriori without requiring new lattice Dirac operator inversions. The method is tested on realistic lattice sizes with light dynamical quarks.

We calculate the light hadron spectrum in full QCD using two plus one flavor Asqtad sea quarks and domain wall valence quarks. Meson and baryon masses are calculated on a lattice of spatial size L ≈ 2.5 fm, and a lattice spacing of a ≈ 0.124 fm, for pion masses as light as mπ ≈ 300 MeV, and compared with the results by the MILC collaboration with Asqtad valence quarks at the same lattice spacing. Two-and three-flavor chiral extrapolations of the baryon masses are performed using both continuum and mixed-action heavy baryon chiral perturbation theory. Both the threeflavor and two-flavor functional forms describe our lattice results, although the low-energy constants from the next-to-leading order SU (3) fits are inconsistent with their phenomenological values. Nextto-next-to-leading order SU (2) continuum formulae provide a good fit to the data and yield and extrapolated nucleon mass consistent with experiment, but the convergence pattern indicates that even our lightest pion mass may be at the upper end of the chiral regime. Surprisingly, our nucleon masses are essentially lineaer in mπ over our full range of pion masses, and we show this feature is common to all recent dynamical calculations of the nucleon mass. The origin of this linearity is not presently understood, and lighter pion masses and increased control of systematic errors will be needed to resolve this puzzling behavior.

Simultaneous enhancement of out-coupling efficiency, internal quantum efficiency, and color purity in thermally activated delayed fluorescence (TADF) emitters is highly desired for the practical application of these materials. We designed and synthesized two isomeric TADF emitters, 2DPyM-mDTC and 3DPyM-pDTC, based on di(pyridinyl)methanone (DPyM) cores as the new electron-accepting units and di(tert-butyl)carbazole (DTC) as the electron-donating units. 3DPyM-pDTC, which is structurally nearly planar with a very small ΔE, shows higher color purity, horizontal ratio, and quantum yield than 2DPyM-mDTC, which has a more flexible structure. An electroluminescence device based on 3DPyM-pDTC as the dopant emitter can reach an extremely high external quantum efficiency of 31.9% with a pure blue emission. This work also demonstrates a way to design materials with a high portion of horizontal molecular orientation to realize a highly efficient pure-blue device based on TADF emitters.

We present results for the isovector axial, scalar and tensor charges g The lattice-QCD calculations were done using nine ensembles of gauge configurations generated by the MILC Collaboration using the HISQ action with 2+1+1 dynamical flavors. These ensembles span three lattice spacings a ≈ 0.06, 0.09 and 0.12 fm and light-quark masses corresponding to the pion masses Mπ ≈ 135, 225 and 315 MeV. High-statistics estimates on five ensembles using the all-mode-averaging method allow us to quantify all systematic uncertainties and perform a simultaneous extrapolation in the lattice spacing, lattice volume and light-quark masses for the connected contributions. Our final estimates, in the MS scheme at 2 GeV, of the isovector charges are g (51)(20). The first error includes statistical and all systematic uncertainties except that due to the extrapolation Ansatz, which is given by the second error estimate. Combining our estimate for g 194(14). Combining our new estimates with precision low-energy experiments, we present updated constraints on novel scalar and tensor interactions, S,T , at the TeV scale.

We present results for the isovector and flavor diagonal tensor charges g needed to probe novel tensor interactions at the TeV scale in neutron and nuclear β-decays and the contribution of the quark electric dipole moment (EDM) to the neutron EDM. The lattice QCD calculations were done using nine ensembles of gauge configurations generated by the MILC collaboration using the HISQ action with 2+1+1 dynamical flavors. These ensembles span three lattice spacings a ≈ 0.06, 0.09 and 0.12 fm and three quark masses corresponding to the pion masses Mπ ≈ 130, 220 and 310 MeV. Using estimates from these ensembles, we quantify all systematic uncertainties and perform a simultaneous extrapolation in the lattice spacing, volume and light quark masses for the connected contributions. The final estimates of the connected nucleon (proton) tensor charge for the isovector combination is g u−d T = 1.020(76) in the MS scheme at 2 GeV. The additional disconnected quark loop contributions needed for the flavor-diagonal matrix elements are calculated using a stochastic estimator employing the truncated solver method with the all-mode-averaging technique. We find that the size of the disconnected contribution is smaller than the statistical error in the connected contribution. This allows us to bound the disconnected contribution and include it as an additional uncertainty in the flavor-diagonal charges. After a continuum extrapolation, we find g