This paper describes a new mutual transformation mode occurred between two aluminium complexes, L1(AlMe2)2·AlMe3and (L1AlMe)2, which were generated upon different solvents and bearing the oxazoline‐amido‐phenolate ligand. Density functional theory (DFT) studies support plausible mechanisms. Their catalytic studies were investigated towards ring opening polymerization of ε‐caprolactone andl‐lactide with the benzyl alcohol as the initiating reagent.

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Ligand precursors for amido/amidate-functionalized triazole-based MIC ligands were synthesized. An initial theoretical calculation confirmed that triazole-based MIC ligands were more promising ligands in terms of their -donating and -acidic properties...