The bimodal-grain-size 7075 aluminium alloys containing varied ratios of large and small 7075 aluminium powders were prepared by spark plasma sintering (SPS). The large powder was 100 ± 15 μm in diameter and the small one was 10 ± 5 μm in diameter. The 7075 aluminium alloys was completely densified under the 500 °C sintering temperature and 60 MPa pressure. The large powders constituted coarse grain zone, and the small powders constituted fine grain zone in sintered 7075 aluminium alloys. The microstructural and microchemical difference between the large and small powders was remained in coarse and fine grain zones in bulk alloys after SPS sintering, which allowed for us to investigate the effects of microstructure and microchemistry on passive properties of oxide film formed on sintered alloys. The average diameter of intermetallic phases was 201.3 nm in coarse grain zone, while its vale was 79.8 nm in fine grain zone. The alloying element content in intermetallic phases in coarse grain zone was 33% to 48% higher than that on fine grain zone. The alloying element depletion zone surrounding intermetallic phases in coarse grain zone showed a bigger width and a more severe element depletion. The coarse grain zone in alloys showed a bigger electrochemical heterogeneity as compared to fine grain zone. The passive film formed on coarse grain zone had a thicker thickness and a point defect density of 2.4 × 1024 m−3, and the film on fine grain zone had a thinner thickness and a point defect density of 4.0 × 1023 m−3. The film resistance was 3.25 × 105 Ωcm2 on coarse grain zone, while it was 6.46 × 105 Ωcm2 on fine grain zone. The passive potential range of sintered alloys increased from 457 mV to 678 mV, while the corrosion current density decreased from 8.59 × 10−7 A/cm2 to 6.78 × 10−7 A/cm2 as fine grain zone increasing from 0% to 100%, which implied that the corrosion resistance of alloys increased with the increasing content of fine grains. The passive film on coarse grain zone exhibited bigger corrosion cavities after pitting initiation compared to that on fine grain zone. The passive film formed on fine grain zone showed a better corrosion resistance. The protectiveness of passive film was mainly determined by defect density rather than the thickness in this work.
Along with the increasing prominence of energy and environmental issues, solar energy has received more and more extensive attention from countries around the world, and the installed capacity of photovoltaic power generation, as one of the main forms of solar energy development, has developed rapidly. Solar energy is by far the largest available source of energy on Earth, the use of solar power photovoltaic system has the advantages of flexible installation, simple maintenance, environmentally friendly, etc., by the world’s attention, especially the grid-connected photovoltaic power generation system has been rapid development. However, photovoltaic power generation itself is intermittent, affected by irradiance and other meteorological factors very drastically, and its own randomness and uncertainty are very large, and its grid connection affects the stability of the entire power grid. Therefore, the short-term prediction of photovoltaic power generation has important practical significance and guiding meaning. Multi-input deep convolutional neural networks belong to deep learning architectures, which use local connectivity, weight sharing, and subpolling operations, making it possible to reduce the number of weight parameters that need to be trained so that convolutional neural networks can perform well even with a large number of layers. In this paper, we propose a multi-input deep convolutional neural network model for PV short-term power prediction, which provides a short-term accurate prediction of PV power system output power, which is beneficial for the power system dispatching department to coordinate the cooperation between conventional power sources and PV power generation and reasonably adjust the dispatching plan, thus effectively mitigating the adverse effects of PV power system access on the power grid. Therefore, the accurate and reasonable prediction of PV power generation power is of great significance for the safe dispatch of power grid, maintaining the stable operation of power grid, and improving the utilization rate of PV power plants.
The impression creep behavior of a lead-based PbSn16Sb16Cu2 alloy was studied at stresses in the range from 15 to 30 MPa and temperatures in the range from 333 to 393 K. XRD, SEM, and EDS techniques were used to analyze microstructural evolutions of the alloy before and after creep at different impression creep conditions. Results show that, in the range of experimental conditions, the calculated stress exponent and the creep activation energy of the alloy are 4.12 and 60.56 kJ mol−1, respectively. Grain boundary diffusion-dominated dislocation climbing is the main impression creep mechanism of PbSn16Sb16Cu2 alloy. Creep rate increases and creep resistance decreases with the increase of temperature and stress, respectively. Two reasons dominate the creep process: first, Sn is largely precipitated from the solid solution in the matrix, which weakens the overall strength of the matrix during the creep process; second, as temperature and stress increase, the atoms are vibrated more fiercely by thermal energy, which results in a softening of the matrix and SnSb phase.
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