Natural clinoptilolite can be used as an ion exchanger for removal of heavy metals and treatment of environmental pollution because of its desirable characteristics of high ion exchange selectivity and resistance to different media.In this work, the potential of natural clinoptilolite from Gördes mines (West Anatolia, Turkey) for the uptake of lead(II), nickel(II), copper(II), and zinc(II), from their single and mixed ion solutions, was evaluated using the batch method. The mineralogical and chemical properties of the sorption material were carried out by X-ray diffraction, X-ray fluoremetry, scanning electron microscopy, and wet analysis.Contact time, initial solution pH, solid-to-liquid ratio, and initial metal cation concentration were determined as single ion sorption parameters. The silicon/aluminum ratio and the theoretical and equivalent exchange capacities, both in single and mixed solutions, were established. Corresponding adsorption constants and distribution coefficients have been found. Water Environ. Res., 79, 329 (2007).
Multiple intelligences theory (MIT) which takes into account students' individual differences has an important role in the teaching and learning process. In this study a novel learning environment based on MIT which takes students' interests and needs into an account has been developed. Many activities were carried out depending on students' intelligence types. The effects of different activities on students' achievements, attitudes toward chemistry and retention of knowledge in periodical features' variety at the 10th class were measured and compared. The comparison between experimental group, which was instructed through MIT learning strategies and materials, and control group thought by traditional methods was observed. The research was applied in the first semester of 2009-2010 education years. The study carried out on 75 high school students in Izmir. The application of the study was lasted for 8 weeks containing methods and tests' practices. Following MIT assessment survey, achievement test and attitude scales were used to analyze its effectiveness. Based on the theories and literature data, an instructional material included concept maps, puzzles, stories, classical music in background, group games, and photos about periodic features' variety as an alternative to traditional written material. As a result of statistical analysis there were significant differences between achievement post-test and attitudes post-test towards chemistry course of control and experimental groups. Consequently, instructional methods needed to be varied so students could use their intellectual strengths to better understand topics, increase their intrinsic motivation, intervention and encourage active student engagement to improve learning at middle school level.
Clay minerals occur widely in nature and play a very important role in agriculture, mineral recovery and chemical manufacturing. Among the many properties which affect clay behaviour, water binding and ion exchanging appear to be the most important. The study of the cation exchange capacity of soils is of great theoretical and practical importance since the CEC determines in many ways the behavior of nutrients, chemical amendments, and many toxic compounds entering the soils. Sorption interactions with montmorillonite and other clay minerals in soils are potantially important mechanisms for attenuating the mobility of heavy metal cations through the subsurface environment. In this work the cation exchange capacity (CEC) of montmorillonite from west Anatolia, and sorptions interactions with montmorillonite for attenuating the mobility of uranium were studied. The CEC value was found to be 77 meq/100 g montmorillonite. The relative importance of test parameters e.g., contact time, particle size, pH and U(+6) aqueous speciation was determined. The results show that sorption on montmorillonite is a funtion of pH depending strongly on the aqueous U(+6) species. It reaches a maximum at near neutral pH(pH~7). At low and at high pH solutions the sorption values of uranium are poor. These sorption values were attributed to the formation of aqueous U(+6) carbonate complexes in alkaline conditions and the ionexchange process between UO2 +2 species and interlayer cations on montmorillonite in acidic solutions.
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