In recent years, for China, animation industry is a relatively new and mature emerging national sunrise industry after animation industry, which appears on the world stage more and more frequently and is widely concerned and valued by people from all over the world. Therefore, this paper innovatively uses the convolutional neural network algorithm to innovate the color matching generation of animation characters and improve the traditional technology of color matching for animation characters. In this paper, we mainly use Generative Adversarial Network (GAN), Deep Convolutional Generative Adversarial Network and VGG model, and multiscale discriminator theory and use ACGAN research method. And we study this paper’s innovative LMV-ACGAN research method, and we have come to the conclusion that other models have higher collapse rate than this model; this model has higher color matching of anime characters. Color matching improves with the increase of convolutional neural network utilization, etc. Moreover, superior and minor reviews of this study are provided to make later researchers understand this study more rationally and objectively.