BACKGROUND: It is hard to control the agricultural products exceeding MRL (maximum residue limit) before forwarding. Therefore, NAQS (National Agricultural Products Quality Management Service, South Korea) established PHRL (pre-harvest residue limit) on agricultural products during their cultivation periods. This study was performed to set the PHRLs of peach during cultivation period, and also to estimate biological half-lives for residues of clothianidin and fluquinconazole. METHODS AND RESULTS: Two groups of peach were treated under Korean GAP (Good Agricultural Practices) with application time, single and triple treatments. Sample was collected over 14days (each after 0, 2, 4, 6, 8, 10, 12, 14 days. 8times), and clothianidin and fluquinconazole were analyzed by HPLC/DAD and GC/ECD, respectively. CONCLUSION: The biological half-life of clothianidin in single treatment and triple treatment was 5.2days and 7.0days. That of fluquinconazole was also 3.9days and 4.1days, respectively. The PHRL of peach on 10days before harvest was 1.4 mg/kg in clothianidin and 1.8 mg/kg in fluquinconazole.

The biological half-life and final residue levels of indoxacarb and pyridalyl were determined in cauliflower over a 10-day cultivation period following applications of a standard (100 g a.i.·ha

Methoxyfenozide and novaluron were sprayed with single and triple treatments separately on peach during cultivation period. Samples were collected over 14 days, 8 times in total (0, 2, 4, 6, 8, 10, 12, 14 days). Methoxyfenozide and novaluron were extracted with acetone and partitioned with dichloromethane, and analyzed by HPLC/DAD. Method Quantitation Limit (MQL) were both 0.005 mg/kg, average recoveries of methoxyfenozide at two fortification levels of 0.05 and 0.25 mg/kg were determined 92.7±2.9% and 102.8±3.1%, and novaluron were 98.2±4.8% and 96.7±9.0%, respectively. The biological half-life of methoxyfenozide was about 4.41 days at single treatment, and 4.24 days at triple treatments. The biological half-life of novaluron was about 14.81 days at single treatment, and 14.50 days at triple treatments. Dissipation of pesticides on peach was influenced by growth dilution effect. In case of application of methoxyfenozide and novaluron following guidelines on safe use of pesticides, the final residue level was predicted to be lower than Maximum Residue Limit (MRL).

BACKGROUND:This study was performed to

The objectives of this study were to provide the basic data of the residue of deltamethrin in the stream water. Deltamethrin was treated on side of Ban-Suk stream and Juk-Dong ditch for hygienic purpose by air spray. The drift concentration of deltamethrin was investigated with different wind speed condition on Ban-Suk stream (A), and the change of residue with time course on Juck-dong ford (B). Also we found the residual change of deltamethrin until 48 hour in Yu-Seong stream confluence (C) where two streams join. Maximum residues of A were 0.17 µg/L (5 min, 200 m) at strong wind speed and 4.42 µg/L (0 min, 25 m) at moderate wind speed according to different wind velocity. Residues of B were 0.15~0.26 µg/L (0~480 min) after spraying, and decreased to a non-detected level after 720 min. Residues of C were 0.15 µg/L (0 min), 0.11 µg/L (1 min) and 0.10 µg/L (12 hr) after spraying, and no residues were detected in any other samples. From these results, it is concluded that deltamethrin residues in water should be rapidly diluted into stream water and affected negligible toxic effect to stream ecosystem.