Dependence of the dimension of the associates of water-soluble tris-malonate of light fullerene -C 60 [= C(COOH) 2 ] 3 in water solutions at 25 • C Investigation of the concentration dependence of the size and type C 60 [=C(COOH) 2 ] 3 aggregation in aqueous solutions at 25 • C was accomplished with the help of a dynamic light scattering method. It was determined that three types of aggregates are realized in the solutions. The average number of C 60 [=C(COOH) 2 ] 3 molecules in smaller aggregates and all types of aggregates were calculated. One can see that over the whole concentration range, from 0.01 to 10 g/dm 3 , aqueous solutions of C 60 [=C(COOH) 2 ] 3 are characterized by sub-micro-heterogeneous behavior (because second-type aggregates with the linear dimensions -hundreds of nm are formed in all solutions). Additionally, the most concentrated solution (C = 10 g/dm 3 ) is characterized by micro-heterogeneous or colloid behavior (because third-type aggregates with the linear dimensions on the order of µm -are formed). In order to describe or explain such behavior, a stepwise aggregation model was invoked.Keywords: tris-malonate of light fullerene, method of the dynamic light scattering.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.