The growth of industrialization, which is forced to use non-renewable energy sources, leads to an increase in environmental pollution. Therefore, it is necessary not only to reduce the use of fossil fuels to meet energy needs but also to replace it with cleaner fuels. Production of hydrogen by splitting water is considered one of the most promising ways to use solar energy. TiO2 is an amphoteric oxide that occurs naturally in several modifications. This review summarizes recent advances of doped TiO2-based photocatalysts used in hydrogen production and the degradation of organic pollutants in water. An intense scientific and practical interest in these processes is aroused by the fact that they aim to solve global problems of energy conservation and ecology.

We examined the response of the pixel detector Timepix3 with silicon sensor to well-defined fast neutron fields. Part of the pixel detector silicon sensor was additionally equipped with a neutron mask of distinct converter regions. The mask consists of separate thermal and fast neutron regions using 6LiF and hydrogen (plastic) converters, respectively. Measurements were performed with mono-energetic fast neutrons produced at D-D and D-T sources from a Van de Graaff accelerator and a neutron generator, respectively. Data were collected with low background including measurements with moderator material to provide a thermalized neutron component. All the signals produced in the detector were analyzed and decomposed in terms of the spectral-tracking response of the pixel detector. The effect of the fast and thermal components of the neutron converter were determined and compared with direct interactions in the silicon sensor which are significant and can be dominant for fast neutrons. We identify and classify the neutron-induced tracks in terms of the broad-type particle-event track classes. A partial overlap is unavoidable with tracks from direct detection of other radiations in particular protons and low-energy light ions as well as X rays. This will limit the neutron-event discrimination in mixed-radiation fields. The detection response according sensor-mask region was examined and calibrated for the investigated neutron fields. The neutron detection efficiency is selectively derived for the detector particle-event classes. This approach enables to enhance the neutron-discrimination and suppress background and unwanted events. This work enables to extend the response matrix of the detector for broad-type radiations to include neutrons both fast and thermal. The results serve to enhance the sensitivity and determine the neutron component in unknown and mixed-radiation fields such as outer space and particle radiotherapy environments.

The cross sections at 5 energy points of the 58Ni(n, α)55Fe reaction were measured in the 4.50 MeV ≤ E n ≤ 5.50 MeV region while those for the 60Ni(n, α)57Fe and 61Ni(n, α)58Fe reactions were measured at E n = 5.00 and 5.50 MeV using the 4.5 MV Van de Graaff accelerator at Peking University. A gridded twin ionization chamber (GIC) was used as the detector, and enriched 58Ni, 60Ni, and 61Ni foil samples were prepared and mounted at the sample changer of the GIC. Three highly enriched 238U3O8 samples inside the GIC were used to determine the relative and absolute neutron fluxes. The neutron energy spectra were obtained through unfolding the pulse height spectra measured by the EJ-309 liquid scintillator. The interference from the low-energy neutrons and impurities in the samples has been corrected. The present data of the 60Ni(n, α)57Fe reaction are the first measurement results below 6.0 MeV, and those of the 61Ni(n, α)58Fe reactions are the first measurement results in the MeV region. The present results have been compared with existing measurements, evaluations, and TALYS-1.9 calculations.