• ). Our aim was to analyse imaging and spectroscopy from multiple different sources using a single self-consistent radiative-transfer model to assess the magnitude of seasonal variability. Globally-averaged stratospheric temperatures measured from methane emission tend towards a quasi-isothermal structure (158-164 K) above the 0.1-mbar level, and are found to be consistent with spacecraft observations of AKARI. This remarkable consistency, despite very different observing conditions, suggests that stratospheric temporal variability, if present, is < ±5 K at 1 mbar and < ±3 K at 0.1 mbar during this solstice period. Conversely, ethane emission is highly variable, with abundance determinations varying by more than a factor of two (from 500 to 1200 ppb at 1 mbar). The retrieved C 2 H 6 abundances are extremely sensitive to the details of the T (p) derivation, although the underlying cause of the variable ethane emission remains unidentified. Stratospheric temperatures and ethane are found to be latitudinally uniform away from the south pole (assuming a latitudinally-uniform distribution of stratospheric methane), with no large seasonal hemispheric asymmetries evident at solstice. At low and mid-latitudes, comparisons of synthetic Voyager-era images with solstice-era observations suggest that tropospheric zonal temperatures are unchanged since the Voyager 2 encounter, with cool mid-latitudes and a warm equator and pole. A re-analysis of Voyager/IRIS 25-50 µm mapping of tropospheric temperatures and para-hydrogen disequilibrium (a tracer for vertical motions) suggests a symmetric meridional circulation with cold air rising at mid-latitudes (sub-equilibrium para-H 2 conditions) and warm air sinking at the equator and poles (super-equilibrium para-H 2 conditions). The most significant atmospheric changes have occurred at high southern latitudes, where zonal temperatures retrieved from 2003 images suggest a polar enhancement of 7-8 K above the tropopause, and an increase of 5-6 K throughout the 70 − 90• S region between 0.1 and 200 mbar. Such a large perturbation, if present in 1989, would have been detectable by Voyager/IRIS in a single scan despite its long-wavelength sensitivity, and we conclude that Neptune's south polar cyclonic vortex increased in strength significantly from Voyager to solstice.
We present and analyze three-dimensional data cubes of Neptune from the OSIRIS integral-field spectrograph on the 10-meter W.M. Keck II telescope, from 26 July 2009. These data have a spatial resolution of 0.035"/pixel and spectral resolution of R∼3800 in the H (1.47-1.80 µm) and K (1.97-2.38 µm) broad bands. We focus our analysis on regions of Neptune's atmosphere that are near-infrared dark -that is, free of discrete bright cloud features. We use a forward model coupled to a Markov chain Monte Carlo algorithm to retrieve properties of Neptune's aerosol structure and methane profile above ∼ 4 bar in these near-infrared dark regions.We construct a set of high signal-to-noise spectra spanning a range of viewing geometries to constrain the vertical structure of Neptune's aerosols in a cloud-free latitude band from 2-12 • N. We find that Neptune's cloud opacity at these wavelengths is dominated by a compact, optically thick cloud layer with a base near 3 bar. Using the pyDISORT algorithm for the radiative transfer and assuming a Henyey-Greenstein phase function, we observe this cloud to be composed of low albedo (single scattering albedo = 0.45 −0.03 ) than those in the deep cloud. When we extend our analysis to 18 cloud-free locations from 20 • N to 87 • S, we observe that the optical depth in aerosols above 0.5 bar decreases by a factor of 2-3 or more at midand high-southern latitudes relative to low latitudes. We also consider Neptune's methane (CH 4 ) profile, and find that our retrievals indicate a strong preference for a low methane relative humidity at pressures where methane is expected to condense. When we include in our fits a parameter for methane depletion below the CH 4 condensation pressure, our preferred solution at most locations is for a methane relative humidity below 10% near the tropopause in addition to methane depletion down to 2.0-2.5 bar. We tentatively identify a trend of lower CH 4 columns above 2.5 bar at mid-and high-southern latitudes over low latitudes, qualitatively consistent with what is found by Karkoschka and Tomasko (2011), and similar to, but weaker than, the trend observed for Uranus.
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