Oscillator strengths and lifetime values for Yb II levels have been calculated within the framework of a pseudo-relativistic Hartree-Fock (HFR) approximation combined with a least-squares fitting of the calculated eigenvalues to the observed energy levels. A considerable amount of configuration interaction together with core-polarization effects have been included in the calculations. The quality of the HFR results has been assessed through a comparison with data obtained using the completely independent relativistic quantum defect orbital (RQDO) method. The theoretical lifetimes reported in the present paper are now in good agreement with most of the accurate experimental values available. The origin of the persisting discrepancies is suggested.
It is shown that the quantum defect orbital (QUO) formalism may be interpreted in terms of the quasirelativistic theory of atoms. In particular, the QUO model potential is equivalent to the effective potential in the hydrogenic secand-order Dirac equation.
An all-electron full configuration interaction ͑FCI͒ calculation of the adiabatic potential energy curves of some of the lower states of BeH molecule is presented. A moderately large ANO basis set of atomic natural orbitals ͑ANO͒ augmented with Rydberg functions has been used in order to describe the valence and Rydberg states and their interactions. The Rydberg set of ANOs has been placed on the Be at all bond distances. So, the basis set can be described as 4s3p2d1f / 3s2p1d͑Be/ H͒ +4s4p2d͑Be͒. The dipole moments of several states and transition dipole strengths from the ground state are also reported as a function of the R Be-H distance. The position and the number of states involved in several avoided crossings present in this system have been discussed. Spectroscopic parameters have been calculated from a number of the vibrational states that result from the adiabatic curves except for some states in which this would be completely nonsense, as it is the case for the very distorted curves of the 3s and 3p
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