Recent results from a three-year multi-disciplinary project on Ancient Egyptian gold jewellery revealed that items of jewellery from the Middle Kingdom to the New Kingdom were manufactured using a variety of alluvial gold alloys. These alloys cover a wide range of colours and the majority contain Platinum Group Elements inclusions. However, in all the gold foils analysed, these inclusions were found to be absent. In this work a selection of gilded wood and leather items and gold foil fragments, all from the excavations by John Garstang at Abydos (primarily from Middle Kingdom graves), were examined using Scanning Electron Microscopy-Energy Disperse Spectroscopy (SEM-EDS), X-Ray Fluorescence (μXRF), Particle Induced X-Ray Emission (µPIXE) and Double Dispersive X-Ray Fluorescence (D 2 XRF). The work allowed us to characterise the composition of the base-alloys and also to reveal the presence of Pt at trace levels, confirming the use of alluvial gold deposits. Corrosion products were also investigated in the foils where surface tarnish was visually observed. Results showed that the differences in the colour of corrosion observed for the foils are related not only to the thickness of the corrosion layer but also to a multi-layer structure containing the various corrosion products.
Reaction with phosphorus
pentachloride under extremely mild conditions is a method of choice for the
synthesis of tertiary chlorides from tertiary alcohols with retention of
configuration.
The most important of the archaeological remains at Wadi el-Hudi are a series of amethyst mines of the pharaonic period. Inscriptions associated with the site were published by Ahmed Fakhry in 1952, but the Middle Kingdom settlement and fortress adjacent to the mines were only briefly described. A preliminary survey of the site, undertaken in November 1992, has provided sufficient new data to allow the archaeological significance of the Wadi el-Hudi mining settlements to begin to be assessed.
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