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There has been significant progress in the area of short-term scheduling of batch processes, including the solution of industrial-sized problems, in the last 20 years. The main goal of this paper is to provide an up-to-date review of the state-of-the-art in this challenging area. Main features, strengths and limitations of existing modeling and optimization techniques as well as other available major solution methods are examined through this paper. We first present a general classification for scheduling problems of batch processes as well as for the corresponding optimization models. Subsequently, the modeling of representative optimization approaches for the different problem types are introduced in detail, focusing on both discrete and continuous time models. A comparison of effectiveness and efficiency of these models is given for two benchmarking examples from the literature. We also discuss two real-world applications of scheduling problems that cannot be readily accommodated using existing methods. For the sake of completeness, other alternative solution methods applied in the field of scheduling are also reviewed, followed by a discussion related to solving large-scale problems through rigorous optimization approaches. Finally, we list available academic and commercial software and briefly address the issue of rescheduling capabilities of the various optimization approaches.Commercial software for batch scheduling, on the other hand, has only begun to emerge over the last few years. Table 6 lists few representative software packages that are currently available in the market, and for which the users only need to specify data on the problem at hand.

In this paper, we address the problem of optimal synthesis of an integrated water system, where water using processes and water treatment operations are combined into a single network such that the total cost of obtaining freshwater for use in the water using operations, and treating wastewater is minimized. A superstructure, which incorporates all feasible design alternatives for water treatment, reuse and recycle, is proposed. We formulate this structure as a non-convex Non-Linear Programming (NLP) problem, which is solved to global optimality. The problem takes the form of a non-convex Generalized Disjunctive Program (GDP) if there is a flexibility of choosing different treatment technologies for the removal of the various contaminants in the wastewater streams. A new deterministic spatial branch and contract algorithm is proposed for optimizing such systems, in which piecewise under-and over-estimators are used to approximate the non-convex terms in the original model to obtain a convex relaxation whose solution gives a lower bound on the global optimum. These lower bounds are made to converge to the solution within a branch and bound procedure. Several examples are presented to illustrate the optimization of these integrated networks using the proposed algorithm.