This paper presents an abbreviated method for estimating exergy destruction in a heat exchanger, requiring only black-box data of the exchanger's inputs and outputs, and eliminating part of the mathematical difficulties associated with the calculations. A well-known model for temperature distributions in an exchanger is adapted for this case, and is used to distinguish between the contributions of the three major causes of the total exergetic loss: heat transfer, fluid friction and energy dissipation to the surroundings. This provides insight into the relative importance of the three, allowing for identification of potential improvements to a given design.Keywords: irreversibility; second law analysis; heat exchanger; thermodynamics; heat transfer

Although CO 2 as refrigerant is well known for having the lowest global warming potential (GWP), and commercial domestic heat pump water heater systems exist, its long expected wide spread use has not fully unfolded. Indeed, CO 2 poses some technological difficulties with respect to conventional refrigerants, but currently, these difficulties have been largely overcome. Numerous studies show that CO 2 heat pump water heaters can improve the coefficient of performance (COP) of conventional ones in the given conditions. In this study, the performances of transcritical CO 2 and R410A heat pump water heaters were compared for an integrated nearly zero-energy building (NZEB) application. The thermodynamic cycle of two commercial systems were modelled integrating experimental data, and these models were then used to analyse both heat pumps receiving and producing hot water at equal temperatures, operating at the same ambient temperature. Within the range of operation of the system, it is unclear which would achieve the better COP, as it depends critically on the conditions of operation, which in turn depend on the ambient conditions and especially on the actual use of the water. Technology changes on each side of the line of equal performance conditions of operation (EPOC), a useful design tool developed in the study. The transcritical CO 2 is more sensitive to operating conditions, and thus offers greater flexibility to the designer, as it allows improving performance by optimising the global system design.

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Three alternatives for integrating a solar field with the bottoming cycle of a combined cycle plant are modeled: parabolic troughs with oil at intermediate and low cycle pressures and Fresnel linear collectors at low cycle pressure. It is assumed that the plant will always operate at nominal conditions, using post-combustion during the hours of no solar resource. A thermoeconomic study of the operation of the plant throughout a year has been carried out. The energy and exergy efficiencies of the plant working in fuel only and hybrid modes are compared. The energy efficiencies obtained are very similar; slightly better for the fuel only mode. The exergy efficiencies are slightly better for hybrid operation than for fuel-only mode, due to the high exergy destruction associated with post-combustion. The values for solar electric efficiency are in line with those of similar studies. The economic study shows that the Fresnel hybridization alternative offers similar performance to the others at a significantly lower cost.