In recent years, an exceptional number of record-shattering temperature extremes have been observed, resulting in significant societal and environmental impacts. The Mediterranean region is particularly thermally vulnerable, frequently suffering from intense and severe heatwaves. Using daily temperature observations from 58 weather stations (NOAA Global Historical Climatology Network daily database) in the Mediterranean area, past heatwave episodes were initially detected. A daily LST time series was developed using Land Surface Temperature (LST) products from Moderate Resolution Imaging Spectroradiometer (MODIS) (Terra & Aqua satellites) for a 19-year period (2002–2020) at the station locations. LST anomalies were identified using percentile-based indices. It was found that remotely sensed-based LST presents the potential for understanding and monitoring heatwave events, as surface thermal anomalies were generally indicative of heatwaves. Approximately 42% (39%) of heatwave days during daytime (nighttime) coincided with LST anomalies; conversely, 51% of daytime LST anomalies overlapped with the exact days of a heatwave (38% at night). Importantly, the degree of association was significantly higher for extremely hot days (up to an 80% match) and long-lasting heatwaves (up to an 85% match). Rising trends in frequency and duration were observed for both heatwaves and LST anomalies. The results advance the understanding of surface-atmosphere coupling during extreme temperature days and reflect the suitability of thermal remote sensing in heatwave preparedness strategies.

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Cities worldwide are getting warmer due to the combined effects of urban heat and climate change. To this end, local policy makers need to identify the most thermally vulnerable areas within cities. The Local Climate Zone (LCZ) scheme highlights local-scale variations; however, its classes, although highly valuable, are to a certain extent generalized in order to be universally applicable. High spatial resolution indicators have the potential to better reflect city-specific challenges; in this paper, the Urban Heat Exposure (UHeatEx) indicator is developed, integrating the physical processes that drive the urban heat island (UHI). In particular, the urban form is modeled using remote sensing and geographical information system (GIS) techniques, and used to estimate the canyon aspect ratio and the storage heat flux. The Bowen ratio is calculated using the aerodynamic resistance methodology and downscaled remotely sensed surface temperatures. The anthropogenic heat flux is estimated via a synergy of top-down and bottom-up inventory approaches. UHeatEx is applied to the city of Athens, Greece; it is correlated to air temperature measurements and compared to the LCZs classification. The results reveal that UHeatEx has the capacity to better reflect the strong intra-urban variability of the thermal environment in Athens, and thus can be supportive for adaptation responses. High-resolution climate projections from the EURO-CORDEX ensemble for the region show that the adverse effects of the existing thermal inequity are expected to worsen in the coming decades.These four decisive parameters for the urban climate (H/W, β, ∆Q S , Q F ) are estimated in this work using meteorological, earth observation, and geographical information system (GIS) data; the Climate 2019, 7, 75 3 of 28 different variables are subsequently incorporated in the UHeatEx composite indicator via principal component analysis (PCA). An additional mapping of the study area using the LCZ scheme is applied, and similarities and differences between UHeatEx and LCZs are discussed. Both results are correlated with air temperature measurements from a network of automatic weather stations (AWSs) in the area under examination, for a six-year period (the warm period months). A qualitative and quantitative analysis examines the presence of thermal inequity in Athens and its relationship with socioeconomic characteristics. The growing importance of thermal indicators in sustainable urban planning, due to climate change, is demonstrated by presenting the simulated future conditions of the city. To this end, high-resolution climate projections from an ensemble of regional climate models (RCMs) were used.

Variations in urban form lead to the development of distinctive intra-urban surface thermal patterns. Previous assessment of the relation between urban structure and satellite-based Land Surface Temperature (LST) has generally been limited to single-city cases. Here, examining 25 European cities (June–August 2017), we estimated the statistical association between surface parameters—the impervious fraction (λimp), the building fraction (λb), and the building height (H)—and the neighborhood scale (1000 × 1000 m) LST variations, as captured by the Moderate Resolution Imaging Spectroradiometer (MODIS) sensor. Correlation analysis, multiple linear regression, and spatial regression were used. As expected, λimp had a consistent positive influence on LSTs. In contrast, the relation of LST with λb and H was generally weaker or negative in the daytime, whereas at night it shifted to a robust positive effect. In particular, daytime LSTs of densely built, high-rise European districts tended to have lower values. This was especially the case for the city of Athens, Greece, where a more focused analysis was conducted, using further surface parameters and the Local Climate Zone (LCZ) scheme. For the urban core of the city, the canyon aspect ratio H/W had a statistically significant (p <0.01) negative relationship with LST by day (Spearman’s rho = −0.68) and positive during nighttime (rho = 0.45). The prevailing intra-urban surface thermal variability in Athens was well reproduced by a 5-day numerical experiment using the meteorological Weather Research and Forecasting Model (WRF) model and a modified urban parameterization scheme. Although the simulation resulted in some systematic errors, the overall accuracy of the model was adequate, regarding the surface temperature (RMSE = 2.4 K) and the near-surface air temperature (RMSE = 1.7 K) estimations.

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