The tetrakis(arylethynyl)silanes 1-4 of which 2-4 are new compounds have been synthesized and determined by single crystal structure analysis to show their tetrahedral molecular geometries reflected in slightly disturbed S 4 symmetry in the crystal lattices. The lattice structures are mainly determined by close packing effects while the interactions of π-stacking type or C-H···π contacts are rather secondary. A similar behaviour is found for the crystal structure of the comparative compound 5 with reference to 4 which lacks the ethynylene units. It is demonstrated that the given molecular constructions are distinguished by a high degree of tetrahedral persistency governing the packing structures.
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