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Structured hybrid materials based on the combination adsorbent-photocatalyst with optimal mechanical resistance and reduced cost, are prepared by extrusion using four different natural silicates with similar mesoporous distribution: sepiolite (S), bentonite (B), mordenite (M) and kaolinite (K). The effect of the textural, morphological and structural properties of plate shaped composites calcined at different temperatures on the adsorption and photocatalytic degradation of formaldehyde in gas phase is analysed.Silicates allows TiO 2 extrusion into flat plates with a content of 50 wt. % of titania. All shaped materials present adequate mechanical resistance to be scaled-up for use in continuous-flow gas-phase catalytic reactors. Thermal treatment at 500 ºC ensures an optimum combination of mechanical, textural and HCHO adsorption properties. The silicates cover part of the TiO 2 particles thus reducing the fraction of TiO 2 actually exposed on the surface of the composites, essential to carried out the photocatalytic process, but they also allow controlling TiO 2 dispersion and the amount of HCHO adsorbed. The HCHO degradation rate is enhanced with all the silicate-TiO 2 composites with respect to that of the benchmark TiO 2. The incorporation of titania into the silicate matrix favors the gas phase removal of HCHO in the following sequence: MTi > KTi > STi > BTi > TiO 2 . The exposed fraction of titania particles and the size of the TiO 2 -anatase crystalline domains determine the efficiency of the hybrid material, which is optimized in high-aluminium kaolinite and mordenite based hybrids.

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Photocatalytic performance is highly dependent on the nature and dispersion of the active sites, playing a crucial role in the optoelectronic and charge-transfer processes. Here, we report stabilized isolated iron on MCM-41 as a highly active catalyst for a photoredox reaction. The unique nature of the single-atom centers exhibit a trichloroethylene conversion per iron site that is almost 5 times higher than that of TiO2. Advanced characterization and theoretical calculations indicate the generation of hydroxyl radicals, through a photoinduced ligand-to-metal charge-transfer mechanism, which act as hole scavengers that lead to the formation of intermediate oxo–iron species (FeO). This intermediate species is the key step in promoting the photocatalytic reactions. Understanding the mechanistic photoredox pathway in isolated active site materials is imperative for developing highly efficient nonprecious photocatalysts for environmental or energy applications.