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We identified dmisteinbergite, the rare trigonal polymorph of CaAl2Si2O8, for the first time in high-grade metamorphic rocks. Dmisteinbergite occurs as a crystallization product of silicate melt inclusions (nanogranitoids) in garnet from three host rocks with different protoliths and re-equilibration conditions, i.e., from 1.0 to 4.5 GPa. Raman spectra and compositions of the dmisteinbergite here investigated are overall identical to those of previously characterized artificial and natural dmisteinbergite. In nanogranitoids, this phase coexists with other metastable polymorphs of feldspar (kumdykolite, kokchetavite) and SiO2 (quartz, cristobalite), recently interpreted as the result of melt undercooling, supersaturation and rapid crystallization of a silicate melt confined in a micrometric pore. Dmisteinbergite formation likely results from a similar process and thus it should be regarded as a kinetically-controlled phase. Moreover, the investigation of dmisteinbergite as well as of other metastable feldspar polymorphs offers new insights into the behavior of natural materials under non-equilibrium conditions.

<p>The Koralpe-Saualpe-Pohorje Complex in the Eastern Alps represents a lithologically heterogenous (U)HP nappe with eclogite lenses embedded in gneissic and metasedimentary rocks. The aim of this project is to determine whether or not tectonic pressure occurred due to differences in viscosity of different lithologies. In this study we investigate in detail the P and T conditions during the formation of the Koralpe–Saualpe-Pohorje Complex along a NW-SE transect. In order to determine the P conditions, quartz inclusions in garnet are investigated with Raman spectroscopy (RSQI barometry). With Zr-in-rutile thermometry, the temperature conditions will be determined. <br />Preliminary results show an overall residual P increase of the quartz inclusions from the northern Saualpe towards Pohorje in the South. The quartz inclusions inside garnet in eclogite show higher residual P with ≤0.72 GPa with respect to the ones in the metasedimentary or gneissic lithologies with ≤0.43 GPa. Elemental maps of garnets in eclogite from three locations show rather variable results with a significant variation of Ca and Mg content in the core, whereas the Mn content is general very low. The metasedimentary and gneissic garnets are predominantly much richer in Fe and show higher Mn with respect to the eclogites.</p>

<p>Melt inclusions have been for almost 150 years an exclusive feature of magmatic rocks. However, intensive research activity in the last decade has shown that melt inclusions, or nanogranitoids, are also a widespread feature of high grade metamorphic rocks. Such inclusions rapidly became fundamental tools to unravel partial melting and melt-related processes taking place during orogenesis.</p><p>One of the latest discoveries in this field has been the identification of nanogranitoids and glass inside the mega almandine-pyrope garnets of Barton Mine (Gore Mountain, NY State, US). These crystals are arguably the world’s largest garnets and occur within garnet hornblendite. Their size is ca. 35 cm in average, while garnet diameters up to 1 m were reported in historical record. Fluid is often invoked in the formation of large crystals, but so far no study has identified clear witnesses for the presence of fluid during garnet formation, e.g. primary fluid inclusions.</p><p>Polycrystalline inclusions of primary nature were instead reported by Darling et al. (1997) to occur inside the garnet: such inclusions are the main target of our study. Their shape ranges from tubular (2-100 µm in length) to negative crystal shape (2-50 µm). They mainly contain cristobalite/quartz, kumdykolite and amphibole. Minor phases such as biotite/phlogopite, enstatite, rutile, ilmenite and a second, Ca-richer plagioclase (or its rare polymorphs dmisteinbergite and svyatoslavite) may be also present. The inclusions were re-homogenized to a silicate-rich glass via piston cylinder experiments at 1.0-1.5 GPa and 925-940°C. Experimental results prove that such inclusions are former droplets of melt, in agreement with the finding of preserved residual glass in one single inclusion before the experimental runs. The melt composition measured in situ via electron microprobe is tonalitic-trondhjemitic with 5-6 wt% H<sub>2</sub>O.</p><p>The identification of melt inclusions points toward a melt rather than a fluid as the medium which favored extreme garnet growth under low nucleation rate conditions. The elements necessary to grow garnets – mainly Fe, Al, Si, Mg- are indeed far more effectively transported by a silicate melt rather than simple aqueous fluid, at least at the limited depth envisioned for this process. In conclusion, the finding of melt inclusions in metamorphic rocks brought us forward along the path toward the solution of the enigma represented by the formation of these giant garnets.</p><p>References<br>Darling, R.S., Chou, I.M., Bodnar, R.J., 1997. An Occurrence of Metastable Cristobalite in High-Pressure Garnet Granulite. Science 276, 91.</p>

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