No abstract

No abstract

No abstract

Lithium diphenylcuprate treatment of methyl 2,3-anhydro-4,6-0-benzylidene-Dpyranosides in which the anomeric substituent and the three-membered rings are cis oriented furnished the expected ~m-diaxial opening products. When the relationship between the anomeric group and the epoxide was trans, the same experimental conditions led only to recovered starting material. Cyan0 cuprates of the type R2CuCNLi2 added stereoselectively to carbohydrate ketones at C-2 and C-3 fmm the opposite side relative to the anomeric substituent

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.