A promising technique of selective lateral epitaxy, namely air-bridged lateral epitaxial overgrowth, is demonstrated in order to reduce the wing tilt as well as the threading dislocation density in GaN thin films. A seed GaN layer was etched to make ridge-stripe along 〈11̄00〉GaN direction and a GaN material was regrown from the exposed (0001) top facet of the ridged GaN seed structures, whose sidewalls and etched bottoms were covered with silicon nitride mask, using low-pressure metalorganic vapor phase epitaxy. The density of dislocations in the wing region was reduced to be <107 cm−2, which was at least two orders of magnitude lower than that of underlying GaN. The magnitude of the wing tilt was determined to be 0.08° by x-ray diffraction (XRD) measurements, which was smaller than other lateral epitaxial overgrown GaN thin films. The full width at half maximum of XRD for the wing region was 138 arc sec, indicating high uniformity of c-axis orientation.
Air-bridged lateral epitaxial growth (ABLEG), a new technique of lateral growth of GaN films, has been developed using low-pressure metalorganic vapor phase epitaxy. A previously grown 1-µm-thick GaN film is grooved along the 1100 GaN direction, and the bottoms of the trenches and the sidewalls are covered with a silicon nitride mask. A free-standing GaN material is regrown from the exposed (0001) surface of the ridged GaN seed structure. Cross-sectional transmission electron microscopy analysis reveals that the dislocations originating from the underlying seed GaN extend straight in the 0001 direction and dislocations do not propagate into the wing region. The wing region also exhibits a smooth surface and the root mean square roughness is found to be 0.088 nm by atomic force microscopy measurement of the (0001) face of the wing region.
Three-dimensional fluid simulations are performed in a horizontal reactor for GaN epitaxy. Attention is paid to the effect of gas flow velocity at the inlet and gas pressure. It is found that the gas flow rate rather than the velocity or the pressure is a key parameter which controls the spatial distribution of streamlines, temperature and gas-phase species. As the gas flow rate increases, the size of return-flow or flow-separation appearing near the gas entrance of the expansion region with a tapering angle increases. This causes velocity peaking near the reactor symmetry plane and complicated transport of gas-phase species along the streamlines of the return-flow. If an optimum gas flow rate which gives minimum return-flow and uniform macroscopic spatial distribution for flow pattern and gas-phase species can be determined, then it is desirable to change the gas flow velocity and the gas pressure on the condition that the gas flow rate is maintained.
Temporally and spatially resolved observations of the nonradiative recombination ͑NR͒ processes of carriers in low dislocated GaN and InGaN/GaN were successfully obtained by using microscopic transient lens spectroscopy. The heat generations and conductivities of NR processes were detected by the signal intensities and the time profiles. We found that the thermal conductivities were not so different at the seed region ͑threading dislocation density (TDD)ϭ1-2ϫ10 9 cm Ϫ2) and the wing region (TDDϭ1-2ϫ10 6 cm Ϫ2) of air-bridged lateral epitaxially grown GaN and InGaN/GaN, but the amount of heat generated at the wing regions was much smaller than that at the seed regions.
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