Photoplethysmography (PPG) is a simple and inexpensive technology used in many smart devices to monitor cardiovascular health. The PPG sensors use LED lights to penetrate into the bloodstream to detect the different blood volume changes in the tissue through skin contact by sensing the amount of light that hits the sensor. Typically, the data are displayed on a graph and it forms the pulse waveform. The information from the produced pulse waveform can be useful in calculating measurements that help monitor cardiovascular health, such as blood pressure. With many more people beginning to monitor their health status on their smart devices, it is extremely important that the PPG signal is accurate. Designing a simple experiment with standard laboratory equipment and commercial sensors, we wanted to find how external factors influence the results. In this study, it was found that external factors, touch force and temperature, can have a large impact on the resulting waveform, so the effects of those factors need to be considered in order for the information to become more reliable.

Semiconductor photocatalysis has received increasing attention because of its potential to address problems related to the energy crisis and environmental issues. However, conventional semiconductor photocatalysts, such as TiO2 and ZnO, can only be activated by ultraviolet light due to their wide band gap. To extend the light absorption into the visible range, the localized surface plasmon resonance (LSPR) effect of noble metal nanoparticles (NPs) has been widely used. Noble metal NPs can couple incident visible light energy to strong LSPR, and the nonradiative decay of LSPR generates nonthermal hot carriers that can be injected into adjacent semiconductor material to enhance its photocatalytic activity. Here we demonstrate that nanoimprint-defined gap plasmonic nanofinger arrays can function as visible light-driven plasmonic photocatalysts. The sub-5 nm gaps between pairs of collapsed nanofingers can support ultra-strong plasmon resonance and thus boost the population of hot carriers. The semiconductor material is exactly placed at the hot spots, providing an efficient pathway for hot carrier injection from plasmonic metal to catalytic materials. This nanostructure thus exhibits high plasmon-enhanced photocatalytic activity under visible light. The hot carrier injection mechanism of this platform was systematically investigated. The plasmonic enhancement factor was calculated using the finite-difference time-domain (FDTD) method and was consistent with the measured improvement of the photocatalytic activity. This platform, benefiting from the precise controllable geometry, provides a deeper understanding of the mechanism of plasmonic photocatalysis.

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