We present a brief history of substrate glasses developed by Corning Incorporated (Corning) for use in Active matrix liquid crystal display (AMLCD) displays. The most basic attributes required of AMLCD substrates include thermal and mechanical stability, precise geometry control, a surface that is basically perfectly smooth, and no inclusions large enough to block a pixel in the final display. In addition, the glasses used as substrate materials must be essentially alkali‐free so that they do not interact chemically or electronically with thin‐film transistors (TFT). Thin, precision sheet was first made at Corning via the slot‐draw process, but was eventually moved to the fusion‐draw process; neither process was originally intended for this application. Alkali‐free glasses were originally developed for electronic applications and lamp envelopes, and considerable research was required to invent compositions that were compatible with the high‐viscosity fusion‐draw process. Examples of the technical challenges presented by the evolving industry requirements are provided, including eliminating arsenic from the substrate glass and reducing the dimensional change during high‐temperature processing of polysilicon‐based TFT.
The fused deposition of ceramics (FDC) technique was used to fabricate piezoelectric ceramic skeletons for the development of piezoelectric composite transducers with 2-2 connectivity for medical imaging. The green parts were designed to have 30 vol% lead zirconate titanate ceramic (PZT-5H) in the final composites. Physical characterization of the sintered samples revealed that 96% of the theoretical density was achieved. Optical microscopy showed that defects due to the FDC mode of deposition, such as small roads and bubbles, were eliminated, because of improvements in powder processing. The electromechanical properties of the final composites were similar to the properties that were obtained for conventionally made composites. A matching layer and a backing layer, as well as wires and an inductor, were added to each FDC composite to fabricate a functional medical imaging transducer. The devices were tested in water using a steel target 3.5 cm thick. Echoes from the target could be detected with all the transducers that were fabricated using FDC. The sensitivities of the transducers were similar to that of a commercial transducer. However, the ringing was much longer than that for a commercial transducer, because the backing layer was not optimized in the transducers that were fabricated using FDC.
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