The results of experimental studies and theoretical basis for wetting solutions surfactants coal particles of small size fractions. On the basis of a physical model on experimental experience shows wetting of the coal particles, resulting from pulverized coal lumps pulverized state to substantially change the structural and surface properties of the coal, which leads to a substantial change in the mechanical, physical and chemical properties of coal.
Abstract. The use of surfactants has a significant impact on the safety of mining operations in order to prevent dynamic processes, prevent dust. The interfacial angle is the main indicator characterizing the interfacial interactions for heterogeneous multicomponent solid bodies, coal and solutions. The problem of development of modern methods for determining the interfacial angle at the coal-water-gas boundary is considered. The results of the research study of the change in the coalliquid-gas interfacial angle are presented. The influence of various coal properties and characteristics on the interfacial angle value is shown. The influence of the interfacial angle on wetting and filtration processes, the features of the experimental methods for the interfacial angle determination are shown. A model of the coal surface consisting of four main components is proposed. The main attention is paid to the moisture content of coal and capillaries as the main factors determining the properties of coal. An analytical method for determining the interfacial angle of coalwater-gas is proposed.
The results of researches of mass transfer in a coal array and its conditions are described in the article. The influence of various physical processes on mass transfer is considered. An essential factor determining the direction of mass transfer in the coal array is the distribution of capillaries by classes. The physical effect for controlling mass transfer is directed at changing the structure of the capillary-porous space of coal. On the other hand, controlling of mass transfer is possible when the fluid properties change: contact angle of watering, coefficient of viscosity, coefficient of surface tension.
The features of gas-liquid fluid filtration processes in a coal mass are discussed and general patterns of mass transfer, extending previously known concepts, are established in the article. It indicates the degree of the influence of wettability, contact angle of wetting on filtration processes. It is assumed the coal-liquid-gas interfacial interactions when infusing the coal mass lead to the deformation of capillary pore space of coal, splitting, swelling and clogging of filter pores and capillaries. A comparison is made between the thermal effect and the effect of surfactants on the deformation processes of the capillary-porous structure of coal. Filtration processes are described by the gas-liquid fluid mass transfer equations. Coal-liquid-gas interfacial processes lead to a change in the state of the interacting phases, which leads to a change in both the filtration properties of the liquid and the filtration properties of a capillary pore space, which is especially characteristic of coal in relation to other rocks. Investigating the interfacial interactions when filtering in the laboratory, it is possible to determine the functions of the variation of the key coefficients in the mass transfer equations. On the basis of such studies, it is possible to predict the results of mass transfer in a coal mass being infused or degassed, as well as the change in the coal mass stress state.
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