Abstract. Continuous in situ measurements of aerosol optical properties were conducted from 29 June to 29 July 2012 in Granada (Spain) with a seven-wavelength Aethalometer, a Multi-Angle Absorption Photometer, and a three-wavelength integrating nephelometer. The aim of this work is to describe a methodology to obtain the absorption coefficients (babs) for the different Aethalometer wavelengths. In this way, data have been compensated using algorithms which best estimate the compensation factors needed. Two empirical factors are used to infer the absorption coefficients from the Aethalometer measurements: C – the parameter describing the enhancement of absorption by particles in the filter matrix due to multiple scattering of light in the filter matrix – and f, the parameter compensating for non-linear loading effects in the filter matrix. Spectral dependence of f found in this study is not very strong. Values for the campaign lie in the range from 1.15 at 370 nm to 1.11 at 950 nm. Wavelength dependence in C proves to be more important, and also more difficult to calculate. The values obtained span from 3.42 at 370 nm to 4.59 at 950 nm. Furthermore, the temporal evolution of the Ångström exponent of absorption (αabs) and the single-scattering albedo (ω0) is presented. On average αabs is around 1.1 ± 0.3, and ω0 is 0.78 ± 0.08 and 0.74 ± 0.09 at 370 and 950 nm, respectively. These are typical values for sites with a predominance of absorbing particles, and the urban measurement site in this study is such. The babs average values are of 16 ± 10 Mm−1 (at 370 nm) and 5 ± 3 Mm−1 (at 950 nm), respectively. Finally, differences between workdays and Sundays have been further analysed, obtaining higher babs and lower ω0 during the workdays than on Sundays as a consequence of the diesel traffic influence.

[1] In this paper, we present a climatological study of atmospheric aerosols in coastal eastern Spain, by means of experimental measurements using a Cimel CE318-2 Sun photometer. The aerosol optical depth, Å ngström wavelength exponent, size distribution, complex refractive index, asymmetry parameter, and single scattering albedo have been retrieved from these measurements. The columnar water content, as an important parameter for understanding aerosol growth, has also been retrieved. Statistical results of the annual and seasonal variability analysis, mainly related to the usual summer maximum turbidity found in the Mediterranean and European regions, are also shown. The results are linked to the character of the site, located in an urban environment, near the Mediterranean Sea, and frequently affected by dusty air masses of Saharan origin.

The in situ procedure for determining the solar calibration constants, originally developed for the PREDE Sun-sky radiometers and based on a modified version of the Langley plot, was applied to a CIMEL instrument located in Valencia, Spain, not integrated into AERONET. Taking into account the different mechanical and electronic characteristics of the two radiometers, the method was adapted to the characteristics of the CIMEL instrument. The iterative procedure for the determination of the solar calibration constants was applied to a 3-year data set. The results were compared with the two sets of experimental calibration constants determined during this period using the standard Langley plot method. The agreement was found to be consistent with the experimental errors, and the method can definitely also be used to determine the solar calibration constant for the CIMEL instrument, improving its calibration. The method can be used provided the radiometer is previously calibrated for diffuse radiance using a standard lamp.

[1] In July 2002 the VELETA-2002 field campaign was held in Sierra Nevada (Granada) in the south of Spain. The main objectives of this field campaign were the study of the influence of elevation and atmospheric aerosols on measured UV radiation. In the first stage of the field campaign, a common calibration and intercomparison between Licor-1800 spectroradiometers and Cimel-318 Sun photometers was performed in order to assess the quality of the measurements from the whole campaign. The intercomparison of the Licor spectroradiometers showed, for both direct and global irradiances, that when the comparisons were restricted to the visible part of the spectrum the deviations were within the instruments' nominal accuracies which allows us to rely on these instruments for measuring physical properties of aerosols at the different measurement stations. A simultaneous calibration on AOD data was performed for the Cimel-318 Sun photometers. When a common calibration and methodology was applied, the deviation was lowered to much less than 0.01 for AOD. At the same time an intercomparison has been made between the AOD values given by the spectroradiometers and the Sun photometers, with deviations obtained from 0.01 to 0.03 for the AOD in the visible range, depending on the channel. In the UVA range, the AOD uncertainty was estimated to be around 0.02 and 0.05 for Cimel and Licor respectively. In general the experimental differences were in agreement with this uncertainty estimation. In the UVB range the AOD measurements should not be used due to maximum instrumental uncertainties.

Abstract. SKYNET is an international research network of ground based sky -sunphotometers for the observation and monitoring of columnar aerosol properties. The algorithm developed by SKYNET is called SKYRAD.pack, and it is used on Prede instruments only. In this study, we have modified the SKYRAD.pack software in order to adapt it to Cimel sunphotometers. A one month database of Cimel data obtained at Burjassot (Valencia, Spain) has been processed with this program and the obtained inversion products have been compared with AERONET retrievals. In general, the differences found were consistent with the individual error assessments for both algorithms. Although the aerosol optical depth compared well for any aerosol burden situation (rmsd of 0.002-0.013 for all wavelengths), inversion products such as the single scattering albedo, refractive index and asymmetry parameter compared better for higher turbidity situations. The comparison performed for cases with an aerosol optical depth at 440 nm over 0.2 showed rms differences of 0.025-0.049 for single scattering albedo, 0.005-0.034 for the real part of refractive index, 0.004-0.007 for the imaginary part of the refractive index and 0.006-0.009 for the asymmetry parameter. With respect to the volume distributions, the comparison also showed a good agreement for high turbidity cases (mainly within the 0.01-7 µm interval) although the already known discrepancy in the extremes of the distribution was still found in 40 % of the cases, in spite of eliminating data and instrumental differences present in previous studies.