In this paper we describe the non-linearity of the NO-H, reaction over Rh surfaces. Rate oscillations have been observed over a stepped (1 1 1) surface with (100) steps, (Rh(533) at low pressures ( I @ Pa) below 500 K, while no oscillations could be observed under these conditions over a Rh( 100) surface and a stepped (1 00) surface with ( 1 1 I ) steps, Rh(71 I). The thermal stability of the N atoms formed during the reaction explains the observed structure sensitivity. Moreover, the results suggest that diffusion of N atoms is needed to synchronise the rate oscillations, a process that is absent on Rh (100) and Rh(71 I). Dans cet article, nous decrivons la non-linearite de la reaction NO-H, sur des surfaces de Rh. Des oscillations de vitesse ont ete observees sur une surface etagee (1 1 1) avec des etages (IOO), Rh(533) a de faibles pressions ( 1 fl Pa) en dessous de 500 K, tandis qu'aucune oscillation n'a pu &tre observee dans ces mCmes conditions sur une surface Rh( 100) et une surface etagee (100) avec des etages (1 1 I), Rh (711). La stabilite thermique des atomes de N formes lors de la reaction explique la sensibilite des structures observees. En outre, les resultats suggerent que la diffusion des atomes de N est necessaire pour synchroniser les oscillations de vitesse, un processus qui est absent sur le Rh(100) et le Rh (711).
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