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The vapor pressures of the fullerenes C60 and C70 have been measured over the temperature range 400–600 °C by the Knudsen-effusion thermogravimetric technique. For C60, a heat of sublimation of 38±1 kcal/mol is obtained, and the value for C70 is 45±1 kcal/mol. The vapor pressure of C60 ranges from 1.8×10−5 and 1.4×10−2 Torr and that of C70 is between 1.4×10−5 and 8.7×10−3 Torr over the temperature range investigated. At 500 °C, the vapor pressure of C60 is about 1035 that of graphite. The entropy of vaporization of C60 obeys Trouton’s rule.

Executive SummaryThe External Flowsheet Review Team (EFRT) expressed concern about the potential for Waste Treatment and Immobilization Plant (WTP) pipe plugging. Per the review's executive summary, "Piping that transports slurries will plug unless it is properly designed to minimize this risk. This design approach has not been followed consistently, which will lead to frequent shutdowns due to line plugging." To evaluate the potential for plugging, critical-velocity tests were performed on several physical simulants to determine if the design approach is conservative. Critical velocity is defined as the point where particles begin to deposit to form a moving bed of particles on the bottom of a straight horizontal pipe during slurry transport operations. The critical velocity depends on the physical properties of the particles, fluid, and system geometry.This report gives the results from critical-velocity testing and provides an indication of slurry stability as a function of fluid rheological properties and transport conditions that are typical of what the plant will see. The experimental results are compared to the WTP design guide on slurry-transport velocity in an effort to confirm minimum waste-velocity and flushing-velocity requirements as established by calculations and critical-velocity correlations in the design guide. The major findings of this testing are as follows:Experimental results indicate that for Newtonian fluids, the design guide is conservative. The design guide is based on the Oroskar and Turian (1980) correlation, a traditional industry-derived equation that focuses on particles larger than 100 m in size. Slurry viscosity has a greater effect on particles with a larger surface area to mass ratio, i.e. smaller particles. The increased viscous forces on small particles result in a smaller critical velocities. Since the Hanford slurry particles generally have large surface area to mass ratios, the reliance on such equations in the 24590-WTP-GPG-M-0058, Rev 0 design guide (Hall 2006) is conservative. Additionally, the use of the 95% percentile particle size as an input to this equation is conservative. The design guide specifies the use of the d 95 density, this term is ambiguous and needs clarification in the design guide. Nonetheless, this value is interpreted to mean the density of the d 95 particle. This density value is irrelevant for critical velocity calculations. Often this value is unknown, and Equation 1 of the 24590-WTP-GPG-M-0058, Rev 0 design guide (Hall 2006) will be used for design purposes. This equation calculates an average or composite density of all solids in the slurry. However, test results indicate that the use of an average particle density as an input to the equation is not conservative. Particle density has a large influence on the overall critical-velocity result returned by the correlation. The viscosity correlation used in the WTP design guide has been shown to be inaccurate for Hanford waste feed materials. Additionally, the recommendation of a 30% minimum margi...

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