Impact of strip gas composition on side stream ammonia stripping, a technology aiming at the reduction of high ammonia levels in anaerobic reactors, was investigated. Evaluation of the effect of oxygen contact during air stripping showed a distinct, though lower than perceived, inhibition of anaerobic microflora. To circumvent, the feasibility and possible constraints of biogas and flue gas as alternatives in side stream stripping were studied. Experiments, with ammonia bicarbonate model solution and digestate, were conducted. It was demonstrated that the stripping performance is negatively correlated to the CO2 level in the strip gas with a progressive performance loss towards higher concentrations. In contrast to biogas with its high CO2 content, the efficiency reduction observed for flue gas was significantly less pronounced. The later provides the additional benefit that its high thermal energy can be re-utilized in the stripping unit and it is therefore considered a viable alternative for air.
Manure represents an exquisite mining opportunity for nutrient recovery (nitrogen and phosphorus), and for their reuse as renewable fertilisers. The ManureEcoMine proposes an integrated approach of technologies, operated in a pilot-scale installation treating swine manure (83.7%) and Ecofrit (16.3%), a mix of vegetable residues. Thermophilic anaerobic digestion was performed for 150 days, the final organic loading rate was 4.6 kgCOD m d, with a biogas production rate of 1.4 Nm m d. The digester was coupled to an ammonia side-stream stripping column and a scrubbing unit for free ammonia inhibition reduction in the digester, and nitrogen recovery as ammonium sulphate. The stripped digestate was recirculated daily in the digester for 15 days (68% of the digester volume), increasing the gas production rate by 27%. Following a decanter centrifuge, the digestate liquid fraction was treated with an ultrafiltration membrane. The filtrate was fed into a struvite reactor, with a phosphorus recovery efficiency of 83% (as orthophosphate). Acidification of digestate could increment the soluble orthophosphate concentration up to four times, enhancing phosphorus enrichment in the liquid fraction and its recovery via struvite. A synergistic combination of manure processing steps was demonstrated to be technologically feasible to upgrade livestock waste into refined, concentrated fertilisers.
It is widely accepted that partial nitrification by ANAMMOX has the potential to become one of the key processes in wastewater treatment. However, large greenhouse gas emissions have been panobserved in many cases. A novel mesh separated reactor, developed to allow continuous operation of deammonification at smaller scale without external biomass selection, was compared to a conventional single-chamber deammonification sequencing batch reactor (SBR), where both were equally-sized pilot-scale reactors. The mesh reactor consisted of an aerated and an anoxic zone separated by a mesh. The resulting differences in the structure of the microbial community were detected by next-generation sequencing. When both systems were operated in a sequencing batch mode, both systems had comparable nitrous oxide emission factors in the range of 4% to 5% of the influent nitrogen load. A significant decrease was observed after switching from sequencing batch mode to continuous operation.
A new approach to perform partial nitritation-anammox in a single tank was investigated. The tank incorporated a mesh (opening size 1.0 × 1.2 mm) as permeable barrier to create two distinct reaction zones (aerated and anoxic). The study reports on the operation and optimization of a 13 L laboratory scale reactor to treat sludge reject water with an NH-N concentration of ∼750 mg·L. Performance throughout 250 days at increasing nitrogen loading rates is presented. The maximum loading rate applied was 1.5 kg NH-N·m·d at a hydraulic retention time of 12 h. Typical composition of the effluent was ∼50 mg·L NH-N; <5-10 mg·L NO-N and ∼60 mg·L NO-N. The corresponding average N removal rates were 85% for total nitrogen and 90% for NH-N, respectively. Process control was very simple. It comprised only regulation of the aeration rate to maintain a pre-set pH (7.1) in the nitritation zone. Performance data clearly indicate that the investigated reactor configuration offers distinct advantages over currently installed processes. It demonstrated high robustness without the need for sophisticated process control. Apparently, the use of a permeable mesh to establish different reaction conditions in a single reactor provides new features of high potential.
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