A Bose-Einstein condensate (BEC) is a state of matter in which extensive collective coherence leads to intriguing macroscopic quantum phenomena. In crystalline semiconductor microcavities, bosonic quasiparticles, known as exciton-polaritons, can be created through strong coupling between bound electron-hole pairs and the photon field. Recently, a non-equilibrium BEC (ref. ) and superfluidity have been demonstrated in such structures. With organic crystals grown inside dielectric microcavities, signatures of polariton lasing have been observed. However, owing to the deleterious effects of disorder and material imperfection on the condensed phase, only crystalline materials of the highest quality have been used until now. Here we demonstrate non-equilibrium BEC of exciton-polaritons in a polymer-filled microcavity at room temperature. We observe thermalization of polaritons and, above a critical excitation density, clear evidence of condensation at zero in-plane momentum, namely nonlinear behaviour, blueshifted emission and long-range coherence. The key signatures distinguishing the behaviour from conventional photon lasing are presented. As no crystal growth is involved, our approach radically reduces the complexity of experiments to investigate BEC physics and paves the way for a new generation of opto-electronic devices, taking advantage of the processability and flexibility of polymers.
The lack of structural symmetry which usually characterizes semiconductor quantum dots lifts the energetic degeneracy of the bright excitonic states and hampers severely their use as high-fidelity sources of entangled photons. We demonstrate experimentally and theoretically that it is always possible to restore the excitonic degeneracy by the simultaneous application of large strain and electric fields. This is achieved by using one external perturbation to align the polarization of the exciton emission along the axis of the second perturbation, which then erases completely the energy splitting of the states. This result, which holds for any quantum dot structure, highlights the potential of combining complementary external fields to create artificial atoms meeting the stringent requirements posed by scalable semiconductor-based quantum technology.
We integrate resonant-cavity light-emitting diodes containing quantum dots onto substrates with giant piezoelectric response. Via strain, the energy of the photons emitted by the diode can be precisely controlled during electrical injection over a spectral range larger than 20 meV. Simultaneously, the exciton fine-structure-splitting and the biexciton binding energy can be tuned to the values required for entangled photon generation.
We study the effect of an external biaxial stress on the light emission of single InGaAs/GaAs(001) quantum dots placed onto piezoelectric actuators. With increasing compression, the emission blueshifts and the binding energies of the positive trion (X+) and biexciton (XX) relative to the neutral exciton (X) show a monotonic increase. This phenomenon is mainly ascribed to changes in electron and hole localization and it provides a robust method to achieve color coincidence in the emission of X and XX, which is a prerequisite for the possible generation of entangled photon pairs via the recently proposed "time reordering" scheme.
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