Abstract. Amorphous silicate particles are generally assumed to be the main dust component in the envelopes of oxygen-rich evolved stars and may be considered the precursors of the pure crystalline enstatite and forsterite particles detected by ISO. We present optical constants in the broad wavelength range 0.2-500 µm for a unique series of pure amorphous Mg-silicates (Mg/Si in the range 0.7-2.4). They have been prepared by the sol-gel process, a chemical technique based on the condensation of Mg-and Si-hydroxides in a liquid phase. The salient feature of these Mg-silicates is the very small content of Si-OH bonds in the silicate network, which considerably reduces the activation energy of crystallization and, thus, decreases the temperature threshold for crystallization as well as crystallization time. The astrophysical relevance of our sol-gel silicates is shown by a comparison of optically thin model spectra based on dust emissivities with ISO-SWS spectra of AGB stars and with 10 µm emission profiles of such stars obtained by ground-based spectroscopy. As paradigmatic cases of AGB spectra with respect to the appearance of the silicate bands, TY Dra (slender bands and deep trough between them) and R Cas (broad bands and widely filled-up trough) were used, for which ISO-SWS spectra are available. The dust emissivity derived from TY Dra can be excellently reproduced by the models, suggesting that the dust grains consist indeed of pure amorphous Mg-silicates. Satisfactory agreement was also found with the mean 10 µm profiles of some groups of AGB stars and supergiants. Spectra with strong dust emission in the silicate trough like R Cas require additional contributions by other dust components, probably oxides. A rough orientation on the spectral properties of such potential trough opacity contributors has been obtained by subtracting a pure silicate spectrum (TY Dra) from a spectrum with a nearly filled trough and a less pronounced 20 µm band (R Cas). In agreement with other amorphous silicates, the spectral index of the new silicate analogues amounts to −2.

The gas-to-dust mass ratios found for interstellar dust within the Solar System, versus values determined astronomically for the cloud around the Solar System, suggest that large and small interstellar grains have separate histories, and that large interstellar grains preferentially detected by spacecraft are not formed exclusively by mass exchange with nearby interstellar gas. Observations by the Ulysses and Galileo satellites of the mass spectrum and flux rate of interstellar dust within the heliosphere are combined with information about the density, composition, and relative flow speed and direction of interstellar gas in the cloud surrounding the solar system to derive an in situ value for the gas-to-dust mass ratio, R g/d =94 +46−38 . This ratio is dominated by the larger near-micron sized grains. Including an estimate for the mass of smaller grains, which do not penetrate the heliosphere due to charged grain interactions with heliosheath and solar wind plasmas, and including estimates for the mass of the larger population of interstellar micrometeorites, the total gas-to-dust mass ratio in the cloud surrounding the Solar System is half this value. Based on in situ data, interstellar dust grains in the of 10 −14 to 10 −13 g mass range are underabundant in the Solar System, compared to an MRN mass distribution scaled to the local interstellar gas density, because such small grains do not penetrate the heliosphere. The gas-to-dust mass ratios are also derived by combining spectroscopic observations of the gas-phase abundances in the nearest interstellar clouds. Measurements of interstellar absorption lines formed in the cloud around the solar system, as seen in the direction of ǫ CMa, give−207 for assumed solar reference abundances, and R g/d =551 +61 −251 for assumed B-star reference abundances. These values exceed the in situ value, suggesting either grain mixing or grain histories are not correctly understood, -4or that sweptup stardust is present. Such high values for diffuse interstellar clouds are strongly supported by diffuse cloud data seen towards λ Sco and 23 Ori, provided B-star reference abundances apply. If solar reference abundances prevail, however, the surrounding cloud is seen to have greater than normal dust destruction compared to higher column density diffuse clouds. The cloud surrounding the Solar System exhibits enhanced gas-phase abundances of refractory elements such as Fe + and Mg + , indicating the destruction of dust grains by shock fronts. The good correlation locally between Fe + and Mg + indicates that the gas-phase abundances of these elements are dominated by grain destruction, while the poor correlation between Fe + and H • indicates either variable gas ionization or the decoupling of neutral gas and dust over parsec scalelengths. These abundances, combined with grain destruction models, indicate that the nearest interstellar material has been shocked with shocks of velocity ∼150 km s −1 . If solar reference abundances are correct, the low R g/d value towards λ Sco may indicat...

Abstract.Crystalline olivines are an important component of silicate dust particles in space. ISO observations revealed the presence of crystalline silicates in comets, protoplanetary accretion disks, and outflows from evolved stars. For the interpretation of astronomical spectra, the relevant material data at a variety of temperatures and over a broad wavelength range, are urgently needed. In contrast to this need, optical properties of the astronomically interesting olivines are scarcely available at present. In order to close this gap, we studied the optical properties of three minerals of the olivine group by reflection spectroscopy on single crystals in the infrared spectral range. We measured the iron endmember (fayalite, Fe2SiO4), an Mg-rich olivine (Mg1.9Fe0.1SiO4), and the magnesium endmember (forsterite, Mg2SiO4) of the (Mg, Fe)2SiO4 series. For a direct comparison with astronomical observations, we present calculated mass absorption coefficients in the Rayleigh limit for different shapes and varying iron content of the dust particles. The laboratory data together with a set of ISO data for envelopes around evolved stars (Molster 2000) are used to constrain the properties of circumstellar silicates. We find that essentially all band positions are shifted to larger wavelengths with increasing iron content. The particle shape influences very significantly the strong bands such as the B1u:ν3 mode that appears as the "11.4 µm" band of forsterite, whereas e.g. the two FIR modes longward of 40 µm remain practically unaffected by the particle shape but shift due to increasing iron content. The comparison with the band positions in ISO spectra points to the presence of olivine crystals strongly elongated along the crystallographic c-axis. In addition, we apply the calculated mass absorption coefficients to evaluate transmission measurements of particles embedded in a matrix -a technique which is frequently used in laboratory astrophysics. All data shown in this paper will be made available in digital form via the electronic database http://www.astro.uni-jena.de.

Amorphous aluminawas produced by a sol-gel technique in order to make available its (Al 2 O 3 ) optical constants for possible astrophysical applications. Gradual annealing showed that the X-ray amorphousness of alumina ended somewhere between 723 and 873 K. Above this transition point, the structure changes into disordered AtMie calculations show that amorphous alumina exhibits a wide Al-O vibrational band, peaking at 11.5È11.8 km and having a steep "" blue ÏÏ and an extended "" red ÏÏ wing. It may be an important contributor to the continuous opacity between the silicate bands in oxygen-rich circumstellar envelopes, whereas it is ruled out for the explanation of the 13 km band.An average 13 km band proÐle was derived from 51 IRAS low-resolution spectra of bright Mira stars and semiregular variables. Its shape, which is satisfactorily represented by a Lorentz proÐle, can be reproduced by Mie calculations with the data of but not with those of The calcu-. lations show that the 13 km band proÐle of is sensitive to grain shape. If is the a-Al 2 O 3 a-Al 2 O 3 absorber, a second band should be present at 21 km.A close correlation was found between the strengths of the 13 km band and the 10 km silicate band. It suggests that the 13 km band carrier could also be somehow connected with silicate dust. Experimental arguments supporting this attribution are presented.

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