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Use of oxygen-enriched combustion air in diesel engines can lead to significant improvements in power density, as well as reductions in particulate emissions, but at the expense of higher NOx emissions. Oxygen enrichment would also lead to lower ignition delays and the opportunity to burn lower grade fuels. Analytical and experimental studies are being conducted in parallel to establish the optimal combination of oxygen level and diesel fuel properties. In this paper, cylinder pressure data acquired on a single-cylinder engine are used to generate heat release rates for operation under various oxygen contents. These derived heat release rates are in turn used to improve the combustion correlation—and thus the prediction capability—of the simulation code. It is shown that simulated and measured cylinder pressures and other performance parameters are in good agreement. The improved simulation can provide sufficiently accurate predictions of trends and magnitudes to be useful in parametric studies assessing the effects of oxygen enrichment and water injection on diesel engine performance. Measured ignition delays, NOx emissions, and particulate emissions are also compared with previously published data. The measured ignition delays are slightly lower than previously reported. Particulate emissions measured in this series of tests are significantly lower than previously reported.