High-resolution electron energy loss spectroscopy (HREELS) has been used to investigate the inelastic electron
scattering processes involved in the excitation of the normal modes of vibration of atomic hydrogen adsorbed
on Si(100) and Ge(100). Detailed measurements as a function of incident electron beam energy allow a clear
distinction to be made between dipole and nondipole excitation processes. The bending and scissor modes of
adsorbed hydrogen are excited predominantly by dipole scattering, but the stretching modes show characteristic
resonances between 3 and 6 eV. The mechanism for these scattering processes is discussed.
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