We present grazing incidence reflectivity measurements in the far infrared region at temperatures above and below Tc for a series of thallium (Tl2Ba2CuO6, Tl2Ba2CaCu2O8) and bismuth (Bi2Sr2CuO6, Bi2Sr2CaCu2O8, and Bi2−xPbxSr2CaCu2O8) based cuprate superconductors. From the spectra, which are dominated by the c-axis phonons, longitudinal frequencies (LO) are directly obtained. The reflectivity curves are well fitted by a series of Lorentz oscillators. In this way the transverse (TO) phonon frequencies were accurately determined. On the basis of the comparative study of the Bi and Tl based cuprates with different number of CuO2 layers per unit cell, we suggest modifications of the assignment of the main oxygen modes. We compare the LO frequencies in Bi2Sr2CaCu2O8 and Tl2Ba2Ca2Cu3O10 obtained from intrinsic Josephson junction characteristics with our measurements, and explain the discrepancy in LO frequencies obtained by the two different methods.
We report on infrared reflectivity measurements of the ab-plane response of superconducting Bi 2 Sr 2 CuO 6 single crystals. The frequency-dependent conductivity has a maximum near 500 cm Ϫ1 at room temperature, which shifts to lower frequency and merges with a Drude peak below 100 K. We attribute the unusual behavior of the midinfrared conductivity to low-frequency transitions between electronic bands of mainly BiO character near the M point. The linear temperature dependence of the low-frequency resistivity can be followed down to approximately 40 K where it saturates.
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