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The direct synthesis of organohalogenosilanes, particularly methyl‐ and phenylchlorosilanes, is the main process for the production of the monomers required for silicone polymers. This complex heterogeneous catalytic reaction involves the interaction of a gaseous component (the organic halide) with two solid components (silicon and copper), the relative quantities of which change as the reaction proceeds. The mechanism of the direct synthesis has not yet been conclusively established. The free‐radical mechanism originally proposed supposes the formation of organic free radicals. On the other hand, the chemisorption mechanism suggested later postulates the dissociative adsorption of the organic halide on the silicon‐copper double center (the silicon and the copper being joined by a chemical bond). The results obtained so far indicate that the chemisorption mechanism is of decisive importance, but it is not impossible that both mechanisms operate simultaneously.

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12l Der Einfluß von Toluol und zugefügtem Methyldichlorsilan auf die Bildung der Methylchlorsilane (II)‐(V) durch Leiten von Methylchlorid (I) über eine durch Tidioxid und Zn‐oxid aktivierte Cu‐Si‐Legierung bei 310°C wird untersucht.