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Atrazine, which is not readily removed by conventional treatment, may cause problems for water utilities in agricultural areas. To help managers, planners, and regulators determine when and where surface waters are likely to be adversely affected by organonitrogen herbicides, the authors analyzed various data on the distribution of these compounds in the lower Kansas River basin. They found that atrazine was the most frequently detected herbicide, was found in the highest concentrations, and was most likely to exceed the maximum contaminant level. The highest atrazine concentrations in the water were measured where the largest amounts of atrazine had been applied to the land, and median concentrations were higher in spring and summer than in fall and winter. Atrazine and chemically similar herbicides are not effectively removed by traditional water treatment. The Kansas State Board of Agriculture has established a pesticide management area to decrease the amount of atrazine that enters surface water.

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A synoptic sampling of five surface-water sites in central Nebraska was conducted by the U.S. Geological Survey as part of its National Water-Quality Assessment Program during storm runoff in May 1992 to relate transport, yields, and concentrations of atrazine to environmental setting. Atrazine was the most extensively applied pesticide in the study unit. Atrazine transport was related to the size of contributing drainage area, quantity of atrazine applied, amount of precipitation, and volume of streamflow. Estimated yields and mean concentrations of atrazine were related to the percentage of cropland in a drainage area. The largest estimated yields and mean concentrations of atrazine in surface water were associated from drainage areas with the highest percentage of cropland, and the smallest was associated with the smallest amount of cropland. Atrazine concentrations increased as streamfiow increased but decreased at or near the time of peak streamflows, perhaps due to dilution. Atrazine concentrations then increased and remained elevated far into the stream recession.Atrazine is a regulated contaminant in fmished public-water supplies. Large concentrations of atrazine could affect the management of public-water supplies because atrazine remains in solution in contrast to many other pesticides that are more easily removed. (KEY TERMS: atrazine; nonpoint source pollution; surface water hydrology; water quality.)