Powder neutron-diffraction measurements on both SmFeAsO and the fluorine-doped superconductor, SmFeAsO 0.85 F 0.15 , show that the Sm sublattice orders magnetically. In both cases we observe a simple layered antiferromagnetic arrangement of the ϳ0.5 B Sm moments. This provides direct evidence that long-ranged magnetic order of the samarium moments coexists with superconductivity in the SmFeAsO 1−x F x system.
Abstract-Primitive meteorites exhibit certain features that are consistent with aqueous and thermal alteration on asteroids, but 0-isotopic analyses show only a modest heavy-isotope shift, interpreted as indicating modification in the nebula. To understand the isotopic effects of asteroidal alteration, we take the L-group ordinary chondrites weathered in Antarctica as an analogue. The data show that alteration is a two-stage process, with an initial phase producing only a negligible isotopic effect. Although surprising, a possible explanation is found when we consider the alteration of terrestrial silicates. Numerous studies report pervasive development of channels a few to a few tens of nanometer wide in the incipient alteration of silicates. We observe a similar texture. Alteration involves a restructuring of clay minerals along these narrow channels, in which access of water is restricted. The clay shows a topotactic relationship to the primary grain, which suggests either epitaxial growth of the clay using the silicate as a substrate or inheritance of the original 0 structure by the clay. Our data suggests the latter: with extensive inheritance of structural polymers by the weathering product, the bulk 0-isotopic composition is comparatively unaffected. This offers an explanation for the lack of an isotopic effect in the weathering of the L chondrites. If substantial modification of chondritic materials may occur without a pronounced isotopic effect, it also reconciles existing 0 analyses of CV chondrites with an asteroidal model of aqueous alteration.
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