A review is presented dealing with the use of carbon paste as an electrode material for electrochemical sensors (3 11 references). It covers mainly publications which appeared during the period 1990-1993; numerous applications demonstrate the widespread applicability of carbon paste in the field of electrochemical analysis, such as voltammetry, amperometry, and potentiometry, but also as an electrode for electrochemical detectors in flow systems.
The formation of thiocholesterol (TC) monolayers on gold has been
studied by ellipsometry, contact angle
measurements, infrared spectroscopy, and cyclic voltammetry.
Subsequent treatment of the TC assembly
with 11-mercaptodeuterioundecanoic acid (MDUA) shows that the average
surface coverage is about 65%
of that of a self-assembled alkanethiolate monolayer and that it has a
large number of molecular defects.
These defects exist because of a mismatch between the size and
shape of the TC molecule and the pinning
distance at the Au(111) crystal lattice. Potential uses of
these defect-rich structures are microelectrode
arrays for electroanalytical and biosensor applications.
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