We calculate and analyse S-wave resonances of helium up to an energy of-0.02 au applying the complex rotation technique. Rydkrg series converging to the hydrogenic thresholds of the Het ion are analysed by quantum defect theory. For moderately excited inner electrons the series converging to different thresholds begin to overlap resulting in perturbed Rydberg series. We find that approximate quantum numbers as well as propensity rules governing the decay of the resonances and the perturbation scheme of the Rydberg aeries prevail. With increasing excitation of the inner electran however, only series whose stiltes tend lo extreme interelectronic angles (cos0) = + I remain regular.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.