The local deformation of the lamellar microstructure of isothermally melted crystallized u noriented polyethylene has been investigated using microindentation hardness (MH). The polymer can be visualized as a composite material consisting of hard and weak elements. The former, the lamellae, are considered to consist of mosaic blocks with liquidlike lattice distortions (paracrystallites). The latter are the interlamellar "amorphous" regions and the mosaic block lateral grain boundaries. The deformation mechanisms beneath the indenter are discussed in the light of current models of plastic deformation. MH is shown to depend on the packing density of the macromolecules in both phases and, as a result, it can be clearly correlated with the macroscopic density of the material. The unit cell expansion and lattice distortions increase in parallel as a consequence of increasing incorporation of chain defects within the lattice. This provokes a conspicuous decrease in the microhardness of the crystals. The increase in lattice distortions is consistent with the concurrent decrease of lamellar thickness and, hence, of the coherently diffracting lattice volume. These results unambiguously emphasize the physical significance of the mosaic block character of the lamellae in determining the micromechanical properties of the material. Finally it is shown that the strain boundary which defines the zone of crystal destruction under the indenter also depends on the average volume of the paracrystallites and on the volume fraction of crystalline material.
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