The magnetic field reorientation of an initially aligned sample of a nematic polymer liquid crystal was followed by proton NMR. Evolution to a metastable (banded) state was considered using a Rheo-NMR technique developed previously. Late stage reorientation was studied by taking into account the dynamics of defects following the formation of splay-bend walls. NMR spectra simulation allowed us to obtain the wall density as a function of time. This result, together with a defectcontrolled wall dissolution model proposed by Rey [ 11, was used to complement the Rheo-NMR technique of measuring the viscoelastic parameters of nematic polymer liquid crystals.
The effect of an applied magnetic field and of the boundaries on the stability of the shear flow of nematic polymer liquid crystals of the tumbling type with respect to the formation of the transient spatially periodic patterns that appears after the start-up of shearing is studied. The unidirectional shear of a nematic director initially uniformly oriented orthogonally to the sample plane and with strong anchoring is considered. The magnetic field is applied orthogonally to the sample plane or in the same direction of the flow. For a given value of the Ericksen number of the flow a critical value of the magnetic-to-viscous energy ratio shows up above which the uniform flow is stable. When the influence of the boundaries may be neglected, an internal Ericksen number that stays constant in a given material is considered such that the wavelength of the periodic pattern is a self-adjusted length. An internal generalized Ericksen number is defined such that it is a universal function of the magnetic-to-viscous energy ratio.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.