Evolving relationships between electrical conductivity (EC) and sodium adsorption ratio (SAR) in reconstructed soils at surface mines have been insufficiently documented in the literature. Some minesoils (i.e., rootzone material) are classified as saline, sodic, or saline-sodic and are considered unsuitable for revegetation. Weatherable minerals such as calcite and gypsum are common in alkaline minesoils and on dissolution tend to mitigate elevated SAR levels by maintaining or increasing electrolytes in the soil and providing sources of exchangeable calcium and magnesium. Topsoils (i.e., coversoils) contribute to mitigation of sodic conditions when soluble cations are translocated from coversoils into the underlying minesoils. This study evaluated the weathering characteristics of minesoils sites from three surface coal mines in northwestern New Mexico and northeastern Arizona. Minesoils were grouped into 11 classes based on EC and SAR. After 6 to 14 yr, differences between upper and lower halves of the coversoils suggest general increases occurred with EC, SAR, chloride (Cl(-)), and sulfate (SO(4)(2-)) with depth. Within the reclaimed minesoils, there were several significant (P < 0.05 or < 0.10) relationships among EC and SAR that related to Minesoil Class. Lower SAR levels with corresponding increases in EC compared to baseline minesoils were more apparent in upper minesoil depths (0-5 and 5-15 cm). Minesoil anion concentrations suggested coversoil leachates and gypsum dissolution influenced EC and SAR chemistry. Over time, chemical changes have increased the apparent stability of the saline and sodic reclaimed minesoils studied thereby reducing risks associated with potential aggregate slaking and clay particle dispersion.

Abstract. Relationships between electrical conductivity (EC) and sodium adsorption ratio (SAR) changes over time in reconstructed soils at surface coal mining operations are insufficiently documented in the literature. Some minesoils (i.e., rootzone material) are classified as saline, sodic, or saline-sodic and have been considered unsuitable rooting media for establishment of native vegetation. Weatherable minerals (e.g., pyrite, calcite, gypsum, and other geologic substrates) commonly present in minesoils can mitigate the effects of elevated SAR levels by maintaining or increasing electrolytes in the soil and provide sources of exchangeable calcium and magnesium. Coversoil (i.e., topsoil) enhances this mitigation through physical and chemical buffering of minesoils. Weathering characteristics of minesoils and rooting patterns of key reclamation species were evaluated at sites from three surface coal mines in northwestern New Mexico and northeastern Arizona.Unweathered minesoils were grouped into 11 classifications based on EC and SAR. Comparison of saturated paste extracts from unweathered and weathered (6 to 14 years after reclamation) minesoils show significant (p < 0.05) reductions in SAR levels and increased EC. Weathering increased the apparent stability of saline and sodic minesoils thereby reducing risks of aggregate slaking and clay particle dispersion. Root density of fourwing saltbush (Atriplex canescens), alkali sacaton (Sporobolus airoides), and Russian wildrye (Psathyrostachys junceus) were generally unaffected by increasing minesoil EC and SAR levels. Saline and sodic minesoils can be successfully reclaimed when covered with topsoil and seeded with salt tolerant plant species.

High altitude, historic, gold and silver tailings deposits, which included a more recent cyanide heap leach operation, were decommissioned, detoxified, re-contoured and revegetated. Detoxification of the heap included rinsing with hydrogen peroxide, lime and ferric chloride, followed by evaporation and land application of remaining solution. Grading included the removal of solution ponds, construction of a geosynthetic/clay lined pond, heap removal and site drainage development. Ameliorative and adaptive revegetation methodologies were utilized. Revegetation was complicated by limited access, lack of topsoil, low pH and elevated metals concentrations in the tailings, and a harsh climate. Water quality sampling results for the first year following revegetation, indicate reclamation activities have contributed to a decrease in metals and sediment loading to surface waters downgradient of the site. Procedures, methodologies and results, following the first year of vegetation growth, are provided.