Conjugated copolymers based on benzodithiophene (BDT) derivatives and thiophene‐quinoxaline‐thiophene (TQT) segments represent an efficient class of light harvesting materials for organic photovoltaic (OPV) applications. Commonly, BDT‐TQT copolymers are synthesized by Stille cross‐coupling polymerization. In this study, alkoxy and thienyl functionalized alternating BDT‐alt‐TQT copolymers are synthesized by direct arylation polymerization (DArP), using Ozawa conditions. An extensive optimization of the reaction conditions such as the catalytic system, solvent, temperature, base, and the concentration of the catalyst is accomplished. The optical and electrochemical properties of the copolymers obtained by DArP are compared to the reference polymers synthesized by Stille cross‐coupling polymerization. Finally, the optimized BDT‐alt‐TQT copolymers are incorporated into organic solar cells as electron donors. The solar cells of the DArP copolymers exhibit power conversion efficiencies up to 80% (rel.) of their Stille cross coupling analogues. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018, 56, 1457–1467

Due to their typical material characteristics, elastomer components are used in almost all areas of engineering. In many cases, these components are subject to large cyclic deformations which result in hysteresis and dissipation-induced self-heating. Further they are exposed to varying ambient temperatures. Increased component temperatures can lead to the loss of a function or to total failure. Therefore, it is important to understand the causes and influences of critical temperatures and to identify them early in the development process under the condition of efficient applicability. In addition to the calculation time and accuracy, this also includes the experimental effort required to identify the material parameters and perform validation measurements. Within this work, the phenomenon of dissipative heating in elastomers is investigated in a numerical study using a modified model of the finite thermoviscoelasticity. For this purpose, a sufficiently simple material model was formulated and implemented under the assumption of the quasi-incompressible material behaviour. Based on this, the type and the characteristic features of the self-heating effect are specifically considered, and its dependence on thermal and mechanical initial and boundary conditions is studied. Thus, a new suitable parameter is introduced, which is particularly useful to identify critical loads. Analogously, the identification of dissipation-sensitive temperature ranges is presented. The utility of the general steadystate equilibrium condition as initial condition is also shown. Furthermore, the influence of the material properties on the steadystate equilibrium is demonstrated for the first time through parameter studies. Based on these findings, recommendations for modelling, calculation and experimental parameterisation are proposed.

This contribution deals with a modified material model of the finite thermoviscoelasticity for the efficient calculation of the dissipative self-heating of elastomer components. The occurrence of critical temperatures, which can lead to loss of functionality or component failure, can be identified at an early stage. Here, the focus lies on industrial applicability, which, in addition to calculation time and quality, also includes the experimental effort required to identify the material parameters. This contribution starts with the formulation of a thermomechanically consistent constitutive model. For this purpose, an appropriate description of the kinematics and the derivation of the constitutive relationships is carried out. These are transferred in a suitable way into the form used by the commercial finite element software ABAQUS and implemented as a thermomechanically fully coupled problem. Furthermore, an industrially applied elastomer material is characterised and the model is parameterized in a special method by selecting the potential function. Finally, the validation of the model and its parameterization are carried out by means of experimental component tests.

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